Artículo

Co-thermolysis: A one-pot synthetic method for novel 2-substituted-5- (trifluoromethoxy)thiophenes

Peláez, Walter JoséIcon ; Argüello, Gustavo AlejandroIcon
Fecha de publicación: 10/2010
Editorial: Pergamon-Elsevier Science Ltd
Revista: Tetrahedron Letters
ISSN: 0040-4039
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

A new 'green' process to obtain trifluoromethoxylated compounds by a gas-phase method has been accomplished. Through it, new 2-substituted-5- (trifluoromethoxy)thiophenes have been obtained in moderate to good yields. Though the reaction occurs in the gas-phase and radicals are involved, an electron transfer mechanism is also postulated to explain the appearance of all detected products. © 2010 Elsevier Ltd. All rights reserved.
Palabras clave: Trifluoromethoxylation , Thiophenes , Electron Transfer Process , Thermolysis
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/69833
URL: https://www.sciencedirect.com/science/article/pii/S0040403910013171
DOI: http://dx.doi.org/10.1016/j.tetlet.2010.07.111
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Articulos(INFIQC)
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Citación
Peláez, Walter José; Argüello, Gustavo Alejandro; Co-thermolysis: A one-pot synthetic method for novel 2-substituted-5- (trifluoromethoxy)thiophenes; Pergamon-Elsevier Science Ltd; Tetrahedron Letters; 51; 40; 10-2010; 5242-5245
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