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dc.contributor.author
Luque, Gisela Carina
dc.contributor.author
Gennero, Maria Rosa
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Chialvo, Abel Cesar
dc.date.available
2019-01-30T20:14:04Z
dc.date.issued
2016-09
dc.identifier.citation
Luque, Gisela Carina; Gennero, Maria Rosa; Chialvo, Abel Cesar; Influence of spontaneous decomposition on the electrochemical formic acid oxidation on a nanostructured palladium electrode; Elsevier Science Inc; Electrochemistry Communications; 70; 9-2016; 69-72
dc.identifier.issn
1388-2481
dc.identifier.uri
http://hdl.handle.net/11336/69068
dc.description.abstract
The formic acid electrooxidation reaction was studied in a flow cell in 1 M HCOOH–0.5 M H2SO4 solution on a palladium film electrode. The evaluation of the open circuit potential (OCP) decay demonstrated that the spontaneous dehydrogenation of formic acid is quickly verified, leading to hydrogen adsorption and absorption. Moreover, the absence of carbon containing adsorbed species was verified by the application of voltammetric stripping after OCP and chronoamperometry. The results obtained demonstrate that the electrocatalytic oxidation of formic acid on Pd takes place through the spontaneous HCOOH dissociative adsorption with CO2 evolution and the adsorbed hydrogen electrooxidation.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science Inc
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
Hcooh Electrooxidation
dc.subject
Hcooh Spontaneous Decomposition, Kinetic Mechanism
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Palladium Electrode
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Otras Ciencias Químicas
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Influence of spontaneous decomposition on the electrochemical formic acid oxidation on a nanostructured palladium electrode
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-01-22T18:51:18Z
dc.journal.volume
70
dc.journal.pagination
69-72
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Luque, Gisela Carina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
dc.description.fil
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
dc.description.fil
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
dc.journal.title
Electrochemistry Communications
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.elecom.2016.07.008
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1388248116301618
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