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dc.contributor.author
Luque, Gisela Carina  
dc.contributor.author
Gennero, Maria Rosa  
dc.contributor.author
Chialvo, Abel Cesar  
dc.date.available
2019-01-30T20:14:04Z  
dc.date.issued
2016-09  
dc.identifier.citation
Luque, Gisela Carina; Gennero, Maria Rosa; Chialvo, Abel Cesar; Influence of spontaneous decomposition on the electrochemical formic acid oxidation on a nanostructured palladium electrode; Elsevier Science Inc; Electrochemistry Communications; 70; 9-2016; 69-72  
dc.identifier.issn
1388-2481  
dc.identifier.uri
http://hdl.handle.net/11336/69068  
dc.description.abstract
The formic acid electrooxidation reaction was studied in a flow cell in 1 M HCOOH–0.5 M H2SO4 solution on a palladium film electrode. The evaluation of the open circuit potential (OCP) decay demonstrated that the spontaneous dehydrogenation of formic acid is quickly verified, leading to hydrogen adsorption and absorption. Moreover, the absence of carbon containing adsorbed species was verified by the application of voltammetric stripping after OCP and chronoamperometry. The results obtained demonstrate that the electrocatalytic oxidation of formic acid on Pd takes place through the spontaneous HCOOH dissociative adsorption with CO2 evolution and the adsorbed hydrogen electrooxidation.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science Inc  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/  
dc.subject
Hcooh Electrooxidation  
dc.subject
Hcooh Spontaneous Decomposition, Kinetic Mechanism  
dc.subject
Palladium Electrode  
dc.subject.classification
Otras Ciencias Químicas  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Influence of spontaneous decomposition on the electrochemical formic acid oxidation on a nanostructured palladium electrode  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2019-01-22T18:51:18Z  
dc.journal.volume
70  
dc.journal.pagination
69-72  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Luque, Gisela Carina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina  
dc.description.fil
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina  
dc.description.fil
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina  
dc.journal.title
Electrochemistry Communications  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.elecom.2016.07.008  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1388248116301618