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dc.contributor.author
Ibrahim, A.
dc.contributor.author
Ley, C.
dc.contributor.author
Allonas, X.
dc.contributor.author
Tarzi, Olga Inés
dc.contributor.author
Chan Yong, A.
dc.contributor.author
Carré, C.
dc.contributor.author
Chevallier, R.
dc.date.available
2019-01-16T20:20:45Z
dc.date.issued
2012-11
dc.identifier.citation
Ibrahim, A.; Ley, C.; Allonas, X.; Tarzi, Olga Inés; Chan Yong, A.; et al.; Optimization of a photopolymerizable material based on a photocyclic initiating system using holographic recording; Royal Society of Chemistry; Photochemical and Photobiological Sciences; 11; 11; 11-2012; 1682-1690
dc.identifier.issn
1474-905X
dc.identifier.uri
http://hdl.handle.net/11336/68170
dc.description.abstract
A set of photoinitiating systems (PIS) for free radical photopolymerization was studied using time-resolved spectroscopic experiments, real-time FTIR and holographic recording. It is shown that the efficiency of the photoinitiating system can be drastically increased when a redox additive is added to the conventional dye/coinitiator system by virtue of photocyclic behaviour. The homogeneous photopolymerization process was found to reach a fast vitrification, limiting the conversion at about 55%. By contrast, holographic recording underlines the differences in photoinitiating system reactivity, allowing diffraction efficiencies close to unity for the most reactive PIS.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Pis
dc.subject
Photopolymerization
dc.subject
Holography
dc.subject.classification
Otras Ciencias Químicas
dc.subject.classification
Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Optimization of a photopolymerizable material based on a photocyclic initiating system using holographic recording
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-01-16T18:18:38Z
dc.journal.volume
11
dc.journal.number
11
dc.journal.pagination
1682-1690
dc.journal.pais
Reino Unido
dc.journal.ciudad
CAMBRIDGE
dc.description.fil
Fil: Ibrahim, A.. Universite de Haute Alsace; Francia
dc.description.fil
Fil: Ley, C.. Universite de Haute Alsace; Francia
dc.description.fil
Fil: Allonas, X.. Universite de Haute Alsace; Francia
dc.description.fil
Fil: Tarzi, Olga Inés. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
dc.description.fil
Fil: Chan Yong, A.. Centre National de la Recherche Scientifique; Francia
dc.description.fil
Fil: Carré, C.. Centre National de la Recherche Scientifique; Francia
dc.description.fil
Fil: Chevallier, R.. Institut Mines-télécom; Francia
dc.journal.title
Photochemical and Photobiological Sciences
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2012/PP/c2pp25099c#!divAbstract
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/c2pp25099c
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