Mostrar el registro sencillo del ítem
dc.contributor.author
Soulé, Ezequiel Rodolfo
dc.contributor.author
Elicabe, Guillermo Enrique
dc.contributor.author
Williams, Roberto Juan Jose
dc.date.available
2019-01-08T16:07:43Z
dc.date.issued
2008-03
dc.identifier.citation
Soulé, Ezequiel Rodolfo; Elicabe, Guillermo Enrique; Williams, Roberto Juan Jose; A rubber-modified thermoplastic where the morphology produced by phase-separation induced by polymerization disappears at high conversions; Springer; Polymer Bulletin; 60; 2-3; 3-2008; 417-423
dc.identifier.issn
0170-0839
dc.identifier.uri
http://hdl.handle.net/11336/67659
dc.description.abstract
An unexpected experimental finding is reported where the primary morphology developed during polymerization-induced phase separation in a rubber-modified thermoplastic practically disappears at high conversions. This process was evidenced by light scattering (LS) and scanning electron microscopy (SEM) for a particular composition of solutions of polyisobutylene oligomers (PIB) in isobornylmethacrylate (IBoMA), during the free-radical polymerization of the monomer. The primary phase separation produced a dispersion of domains rich in PIB containing significant amounts of the monomer (IBoMA). Polymerization of the monomer in these domains occurred at high overall conversions producing the filling of dispersed domains with a PIBoMA-PIB blend that could not be distinguished from the matrix. Under these conditions the final material had the appearance of a homogeneous blend. © 2007 Springer-Verlag.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Springer
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Phase Separation
dc.subject
Light Scattering
dc.subject
Inverse Problem
dc.subject
Polymer
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
A rubber-modified thermoplastic where the morphology produced by phase-separation induced by polymerization disappears at high conversions
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-01-02T18:28:23Z
dc.journal.volume
60
dc.journal.number
2-3
dc.journal.pagination
417-423
dc.journal.pais
Alemania
dc.journal.ciudad
Berlin
dc.description.fil
Fil: Soulé, Ezequiel Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
dc.description.fil
Fil: Elicabe, Guillermo Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
dc.description.fil
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
dc.journal.title
Polymer Bulletin
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1007/s00289-007-0882-6
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s00289-007-0882-6
Archivos asociados