Mostrar el registro sencillo del ítem

dc.contributor.author
Blanco, Maria Belen  
dc.contributor.author
Teruel, Mariano Andres  
dc.date.available
2019-01-04T12:40:52Z  
dc.date.issued
2011-01  
dc.identifier.citation
Blanco, Maria Belen; Teruel, Mariano Andres; Atmospheric photodegradation of ethyl vinyl ketone and vinyl propionate initiated by OH radicals; Elsevier Science; Chemical Physics Letters; 502; 4-6; 1-2011; 159-162  
dc.identifier.issn
0009-2614  
dc.identifier.uri
http://hdl.handle.net/11336/67371  
dc.description.abstract
Rate coefficients for the reactions of hydroxyl radicals with ethyl vinyl ketone and vinyl propionate were determined at 298 K and atmospheric pressure. A collapsible chamber with gas chromatography was used to perform relative kinetic determinations. The room temperature rate coefficients (in cm 3 molecule-1 s-1) were: k1(OH + CH2CHC(O)CH2CH3) = (2.90 ± 0.79) × 10-11 and k2(OH + CH2CHOC(O)CH 2CH3) = (2.46 ± 0.28) × 10-11. This is the first kinetic study of title reactions under atmospheric conditions. The kinetic data were compared with previous literature values, used to calculate atmospheric lifetimes and correlated with the ionization potential of the unsaturated compounds. © 2010 Elsevier B.V. All rights reserved.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Relative Kinetics  
dc.subject
Unsaturated Vocs  
dc.subject
Simulation Chambers  
dc.subject
Oh Radicals  
dc.subject.classification
Otras Ciencias Químicas  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Atmospheric photodegradation of ethyl vinyl ketone and vinyl propionate initiated by OH radicals  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2019-01-02T19:10:59Z  
dc.journal.volume
502  
dc.journal.number
4-6  
dc.journal.pagination
159-162  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina  
dc.description.fil
Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina  
dc.journal.title
Chemical Physics Letters  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009261410016465  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.cplett.2010.12.059  

Archivos asociados
Thumbnail
 
Tamaño: 436.0Kb
Formato: PDF
.