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dc.contributor.author
Sieben, Juan Manuel
dc.contributor.author
Duarte, Marta María Elena
dc.contributor.author
Mayer, Carlos Enrique
dc.date.available
2018-12-21T14:09:16Z
dc.date.issued
2011-03
dc.identifier.citation
Sieben, Juan Manuel; Duarte, Marta María Elena; Mayer, Carlos Enrique; Influence of alcohol additives in the preparation of electrodeposited Pt-Ru catalysts on oxidized graphite cloths; Elsevier Science Sa; Journal of Alloys and Compounds; 509; 9; 3-2011; 4002-4009
dc.identifier.issn
0925-8388
dc.identifier.uri
http://hdl.handle.net/11336/66890
dc.description.abstract
Carbon supported Pt-Ru catalysts were prepared by multiple cycles of potentiostatic pulses from aqueous diluted chloroplatinic acid and ruthenium chloride solutions in the presence of ethanol or ethylene glycol at pH 2 and 5. SEM images showed that the metallic deposit prepared at pH 2 consisted of large irregular agglomerates, whereas smaller globular particles were obtained at pH 5. In addition, the average particle size was considerably decreased in the presence of the stabilizers. The supported Pt-Ru alloys were tested as catalysts for methanol electro-oxidation in acid media. Electrocatalytic activity measurements indicated that the most active electrode was obtained with ethylene glycol as additive at pH 5. © 2011 Elsevier B.V. All rights reserved.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science Sa
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Electrodeposition
dc.subject
Ethanol
dc.subject
Ethylene Glycol
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Methanol Electro-Oxidation
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Pt-Ru Alloys
dc.subject.classification
Recubrimientos y Películas
dc.subject.classification
Ingeniería de los Materiales
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Influence of alcohol additives in the preparation of electrodeposited Pt-Ru catalysts on oxidized graphite cloths
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-12-20T18:16:05Z
dc.journal.volume
509
dc.journal.number
9
dc.journal.pagination
4002-4009
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Sieben, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
dc.description.fil
Fil: Duarte, Marta María Elena. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
dc.description.fil
Fil: Mayer, Carlos Enrique. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
dc.journal.title
Journal of Alloys and Compounds
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0925838811000181
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.jallcom.2011.01.003
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