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dc.contributor.author
Pons, María Josefina  
dc.contributor.author
Franchini, Marta Beatriz  
dc.contributor.author
Giusiano, Adolfo Eugenio  
dc.contributor.author
Patrier, Patricia  
dc.contributor.author
Beaufort, Daniel  
dc.contributor.author
Impiccini, Agnes  
dc.contributor.author
Rainoldi, Ana Laura  
dc.contributor.author
Meinert, Lawrence  
dc.date.available
2018-12-13T22:13:44Z  
dc.date.issued
2017-01  
dc.identifier.citation
Pons, María Josefina; Franchini, Marta Beatriz; Giusiano, Adolfo Eugenio; Patrier, Patricia; Beaufort, Daniel; et al.; Alteration halos in the Tordillos sediment-hosted copper deposit of the Neuquén Basin, Argentina; Elsevier Science; Ore Geology Reviews; 80; 1-2017; 691-715  
dc.identifier.issn
0169-1368  
dc.identifier.uri
http://hdl.handle.net/11336/66480  
dc.description.abstract
The Tordillos sediment-hosted Cu deposit is located in the north-central sector of the Huincul High structure, in the Neuquén Basin, Argentina. It is hosted in sedimentary rocks of the Huincul Formation, an Upper Cretaceous redbed sequence deposited in a fluvial environment. Field mapping, petrography, and chemical analysis of the authigenic clay, sulfate, carbonate, and sulfide minerals at Tordillos have identified systematic variation in alteration and paragenesis with time and with respect to the main feeder zones. The alteration associated with Cu mineralization provides evidence of a multistage infiltration of fluids spatially associated with paleo-hydrocarbon migration driven by Tertiary tectonism. Early diagenesis formed hematite, kaolinite, and calcite1 that have been preserved in the reddish brown mudstones. Later influx of hydrocarbons and warm, reduced formation waters from deeper reservoir rocks is associated with dissolution of early cements and clasts and precipitation of new minerals. In the thickest paleo-channels of the Huincul Formation, dissolution of early cements (hematite, kaolinite, calcite1 and barite1) and clasts locally increased the porosity of sandstones up to 24% and destroyed hematite that changed sandstones and conglomerates from red to yellowish-grey. Bitumen impregnations are abundant along with calcite2, 3, and 4, pyrite, minor montmorillonite, quartz overgrowth, and coarse barite2 crystals with primary organic fluid inclusions at the contact with hydrocarbon tubes. The MnO enrichment of calcite in stages 3 and 4 reflects their precipitation under reduced conditions. Grey and greenish-grey sandstones with montmorillonite, V-hematite, smectite-chlorite group minerals and pyrite, respectively are exposed between the reddish-brown mudstones and the yellowish-grey sandstones and conglomerates. The grey and greenish-grey horizons are representative of abrupt changes in Eh-pH conditions, between regional early oxidizing solutions responsible for the formation of early diagenetic redbeds and later infiltration of reducing fluids responsible for alteration of sedimentary rocks. Copper mineralization is located inside the altered sandstones and conglomerates zones, forming halos surrounding vertical tubes containing bitumen. These tubes are interpreted as the conduits through which migrated hydrocarbons, formation waters, and subsequent chloride and metal-rich fluids. In these places, pyrite, calcite, and barite cements of the altered rocks, have been dissolved and replaced by copper-rich sulfides and then by late supergene Cu minerals. Interconnection among stacked permeable paleo-channels in the mid-section of the Huincul Formation facilitated the migration of several generations of fluids during early diagenesis, hydrocarbon up flow, and exhumation of the Neuquén Group, resulting in the development of alteration halos and Cu mineralization that can be used, both in outcrop and drill core, during exploration for sediment-hosted Cu mineralization.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Cu Mineralization  
dc.subject
Hydrocarbons Migration  
dc.subject
Redbed  
dc.subject
Redox Reactions  
dc.subject.classification
Meteorología y Ciencias Atmosféricas  
dc.subject.classification
Ciencias de la Tierra y relacionadas con el Medio Ambiente  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Alteration halos in the Tordillos sediment-hosted copper deposit of the Neuquén Basin, Argentina  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2018-10-23T20:18:55Z  
dc.journal.volume
80  
dc.journal.pagination
691-715  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Pons, María Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación en Paleobiología y Geología; Argentina. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Geología y Petróleo; Argentina  
dc.description.fil
Fil: Franchini, Marta Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación en Paleobiología y Geología; Argentina. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Geología y Petróleo; Argentina  
dc.description.fil
Fil: Giusiano, Adolfo Eugenio. Provincia de Neuquén. Dirección Provincial de Hidrocarburos y Energía; Argentina  
dc.description.fil
Fil: Patrier, Patricia. Université de Poitiers; Francia  
dc.description.fil
Fil: Beaufort, Daniel. Université de Poitiers; Francia  
dc.description.fil
Fil: Impiccini, Agnes. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Geología y Petróleo; Argentina  
dc.description.fil
Fil: Rainoldi, Ana Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación en Paleobiología y Geología; Argentina. Universidad Nacional del Sur. Departamento de Geología; Argentina  
dc.description.fil
Fil: Meinert, Lawrence. James Cook University; Australia  
dc.journal.title
Ore Geology Reviews  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.oregeorev.2016.06.011  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://www.sciencedirect.com/science/article/pii/S0169136815303024