Artículo
Influence of exchange in NMR pore size/relaxation correlation experiments
Fecha de publicación:
10/2018
Editorial:
Elsevier Science
Revista:
Microporous and Mesoporous Materials
ISSN:
1387-1811
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The influence of molecular exchange in porous polymeric systems on experiments that simultaneously correlate and determine pore length scales and surface relaxivities is studied. Pore length scales are determined by taking advantage of the internal field gradients generated by the difference in magnetic susceptibility between the polymer matrix and the contained water, namely the Decay Due to the Internal Field experiment. Transverse relaxation is codified in the detection period thus enabling correlation with the pore length. For the hierarchical very well connected porous polymer system, the considerable molecular exchange of water between different environments renders signals in the two-dimensional maps that make the determination of the surface relaxivity a complex problem.
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Articulos(IFEG)
Articulos de INST.DE FISICA ENRIQUE GAVIOLA
Articulos de INST.DE FISICA ENRIQUE GAVIOLA
Citación
Silletta, Emilia Victoria; Franzoni, Maria Belen; Monti, Gustavo Alberto; Acosta, Rodolfo Héctor; Influence of exchange in NMR pore size/relaxation correlation experiments; Elsevier Science; Microporous and Mesoporous Materials; 269; 10-2018; 17-20
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