Show simple item record

dc.contributor.author Cobos, Carlos Jorge
dc.contributor.author Hintzer, K.
dc.contributor.author Sölter, L.
dc.contributor.author Tellbach, E.
dc.contributor.author Thaler, A.
dc.contributor.author Troe, J.
dc.date.available 2018-11-08T18:21:45Z
dc.date.issued 2017-04
dc.identifier.citation Cobos, Carlos Jorge; Hintzer, K.; Sölter, L.; Tellbach, E.; Thaler, A.; et al.; Shock wave studies of the pyrolysis of fluorocarbon oxygenates. II. the thermal dissociation of C4F8O; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 19; 4; 4-2017; 3159-3164
dc.identifier.issn 1463-9076
dc.identifier.uri http://hdl.handle.net/11336/64000
dc.description.abstract The thermal decomposition of octafluorooxalane, C4F8O, to C2F4 + CF2 + COF2 has been studied in shock waves highly diluted in Ar between 1300 and 2200 K. The primary dissociation was shown to be followed by secondary dissociation of C2F4 and dimerization of CF2. The primary dissociation was found to be in its falloff range and falloff curves were constructed. The limiting low and high pressure rate constants were estimated and compared with modelling results. Quantum-chemical calculations identified possible reaction pathways, either leading directly to the final products of the reaction or passing through an open-chain CF2CF2CF2 intermediate which dissociates in a second step.
dc.format application/pdf
dc.language.iso eng
dc.publisher Royal Society of Chemistry
dc.rights info:eu-repo/semantics/restrictedAccess
dc.rights.uri https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject.classification Otras Ciencias Químicas
dc.subject.classification Ciencias Químicas
dc.subject.classification CIENCIAS NATURALES Y EXACTAS
dc.title Shock wave studies of the pyrolysis of fluorocarbon oxygenates. II. the thermal dissociation of C4F8O
dc.type info:eu-repo/semantics/article
dc.type info:ar-repo/semantics/artículo
dc.type info:eu-repo/semantics/publishedVersion
dc.date.updated 2018-10-22T22:30:34Z
dc.journal.volume 19
dc.journal.number 4
dc.journal.pagination 3159-3164
dc.journal.pais Reino Unido
dc.description.fil Fil: Cobos, Carlos Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
dc.description.fil Fil: Hintzer, K.. Dyneon GmbH; Alemania
dc.description.fil Fil: Sölter, L.. Universität Göttingen; Alemania
dc.description.fil Fil: Tellbach, E.. Universität Göttingen; Alemania
dc.description.fil Fil: Thaler, A.. Dyneon GmbH; Alemania
dc.description.fil Fil: Troe, J.. Universität Göttingen; Alemania. Max-Planck-Institut für Biophysikalische Chemie; Alemania
dc.journal.title Physical Chemistry Chemical Physics
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/C6CP06822G
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/CP/C6CP06822G
dc.conicet.fuente Crossref


Archivos asociados

Icon
Blocked Acceso no disponible

This item appears in the following Collection(s)

Show simple item record

info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)