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dc.contributor.author
Cobos, Carlos Jorge
dc.contributor.author
Hintzer, K.
dc.contributor.author
Sölter, L.
dc.contributor.author
Tellbach, E.
dc.contributor.author
Thaler, A.
dc.contributor.author
Troe, J.
dc.date.available
2018-11-08T18:21:45Z
dc.date.issued
2017-04
dc.identifier.citation
Cobos, Carlos Jorge; Hintzer, K.; Sölter, L.; Tellbach, E.; Thaler, A.; et al.; Shock wave studies of the pyrolysis of fluorocarbon oxygenates. II. the thermal dissociation of C4F8O; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 19; 4; 4-2017; 3159-3164
dc.identifier.issn
1463-9076
dc.identifier.uri
http://hdl.handle.net/11336/64000
dc.description.abstract
The thermal decomposition of octafluorooxalane, C4F8O, to C2F4 + CF2 + COF2 has been studied in shock waves highly diluted in Ar between 1300 and 2200 K. The primary dissociation was shown to be followed by secondary dissociation of C2F4 and dimerization of CF2. The primary dissociation was found to be in its falloff range and falloff curves were constructed. The limiting low and high pressure rate constants were estimated and compared with modelling results. Quantum-chemical calculations identified possible reaction pathways, either leading directly to the final products of the reaction or passing through an open-chain CF2CF2CF2 intermediate which dissociates in a second step.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject.classification
Otras Ciencias Químicas
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Shock wave studies of the pyrolysis of fluorocarbon oxygenates. II. the thermal dissociation of C4F8O
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-10-22T22:30:34Z
dc.journal.volume
19
dc.journal.number
4
dc.journal.pagination
3159-3164
dc.journal.pais
Reino Unido
dc.description.fil
Fil: Cobos, Carlos Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
dc.description.fil
Fil: Hintzer, K.. Dyneon GmbH; Alemania
dc.description.fil
Fil: Sölter, L.. Universität Göttingen; Alemania
dc.description.fil
Fil: Tellbach, E.. Universität Göttingen; Alemania
dc.description.fil
Fil: Thaler, A.. Dyneon GmbH; Alemania
dc.description.fil
Fil: Troe, J.. Universität Göttingen; Alemania. Max-Planck-Institut für Biophysikalische Chemie; Alemania
dc.journal.title
Physical Chemistry Chemical Physics
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/C6CP06822G
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/CP/C6CP06822G


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