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dc.contributor.author
Acebal, Carolina Cecilia
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dc.contributor.author
Sklená?ová, Hana
dc.contributor.author
Skrlíková, Jana
dc.contributor.author
Srámková, Ivana
dc.contributor.author
Andruch, Vasil
dc.contributor.author
Balogh, Ioseph S.
dc.contributor.author
Solich, Petr
dc.date.available
2018-11-07T20:08:37Z
dc.date.issued
2012-07
dc.identifier.citation
Acebal, Carolina Cecilia; Sklená?ová, Hana; Skrlíková, Jana; Srámková, Ivana; Andruch, Vasil; et al.; Application of DV-SIA manifold for determination of thiocyanate ions in human saliva samples; Elsevier Science; Talanta; 96; 7-2012; 107-112
dc.identifier.issn
0039-9140
dc.identifier.uri
http://hdl.handle.net/11336/63933
dc.description.abstract
An automated, simple and inexpensive double-valve sequential injection analysis (DV-SIA) spectrophotometic method with online liquid-liquid extraction, for the determination of thiocyanate has been developed. The method has been based on the formation of an ion associate between thiocyanate and Astra Phloxine in acidic medium, and the subsequent extraction with amylacetate. The absorbance of the extracted ion associate was measured at 550 nm. The calibration function was linear in the range 0.05-0.50 mmol L-1 and the regression equation was A = (1.887 ± 0.053) [SCN- mmol L-1] + (0.037 ± 0.014) with a correlation coefficient of 0.995. The precision of the proposed method was evaluated by the relative standard deviation (RSD) values at two concentration levels: 0.20 and 0.50 mmol L-1. The obtained results were 1.0 and 2.8%, respectively, for the intra-day precision, and 4.2 and 3.8%, respectively for the inter-day precision. The calculated detection limit was 0.02 mmol L-1. The developed method has been successfully applied for determining thiocyanate ions in human saliva samples. © 2012 Elsevier B.V. All rights reserved.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Biological Samples
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Dv-Sia
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Extraction
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Thiocyanate
dc.subject.classification
Otras Ciencias Químicas
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dc.subject.classification
Ciencias Químicas
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dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
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dc.title
Application of DV-SIA manifold for determination of thiocyanate ions in human saliva samples
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-11-05T19:04:46Z
dc.journal.volume
96
dc.journal.pagination
107-112
dc.journal.pais
Países Bajos
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dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Acebal, Carolina Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina. Charles University; República Checa
dc.description.fil
Fil: Sklená?ová, Hana. Charles University; República Checa
dc.description.fil
Fil: Skrlíková, Jana. Charles University; República Checa. University of Pavol Jozef Šafárik; República Checa
dc.description.fil
Fil: Srámková, Ivana. Charles University; República Checa
dc.description.fil
Fil: Andruch, Vasil. University of Pavol Jozef Šafárik; República Checa
dc.description.fil
Fil: Balogh, Ioseph S.. College of Nyíregyház; Hungría
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Fil: Solich, Petr. Charles University; República Checa
dc.journal.title
Talanta
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1016/j.talanta.2012.01.021
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0039914012000276
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