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dc.contributor.author
Insausti, Matías
dc.contributor.author
de Araújo Gomes, Adriano
dc.contributor.author
Camiña, José Manuel
dc.contributor.author
de Araújo, Mario Cesar Ugulino
dc.contributor.author
Fernández Band, Beatriz Susana
dc.date.available
2018-11-07T17:37:44Z
dc.date.issued
2017-03
dc.identifier.citation
Insausti, Matías; de Araújo Gomes, Adriano; Camiña, José Manuel; de Araújo, Mario Cesar Ugulino; Fernández Band, Beatriz Susana; Fluorescent fingerprints of edible oils and biodiesel by means total synchronous fluorescence and Tucker3 modeling; Pergamon-Elsevier Science Ltd; Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy; 175; 3-2017; 185-190
dc.identifier.issn
1386-1425
dc.identifier.uri
http://hdl.handle.net/11336/63891
dc.description.abstract
The present work proposes the use of total synchronous fluorescence spectroscopy (TSFS) as a discrimination methodology for fluorescent compounds in edible oils, which are preserved after the transesterification processes in the biodiesel production. In the same way, a similar study is presented to identify fluorophores that do not change in expired vegetal oils, to associate physicochemical parameters to fluorescent measures, as contribution to a fingerprint for increasing the chemical knowledge of these products. The fluorescent fingerprints were obtained by Tucker3 decomposition of a three-way array of the total synchronous fluorescence matrices. This chemometric method presents the ability for modeling non-bilinear data, as Total Synchronous Fluorescence Spectra data, and consists in the decomposition of the three way data arrays (samples × Δλ × λ excitation), into four new data matrices: A (scores), B (profile in Δλ mode), C (profile in spectra mode) and G (relationships between A, B and C). In this study, 50 samples of oil from soybean, corn and sunflower seeds before and after its expiration time, as well as 50 biodiesel samples obtained by transesterification of the same oils were measured by TSFS. This study represents an immediate application of chemical fingerprint for the discrimination of non-expired and expired edible oils and biodiesel. This method does not require the use of reagents or laborious procedures for the chemical characterization of samples.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Pergamon-Elsevier Science Ltd
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
Biodiesel And Edible Oils Discrimination
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Fluorescent Fingerprints
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Total Synchronic Fluorescence Spectroscopy
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Tucker3 Model
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Otras Ciencias Químicas
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Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.subject.classification
Otras Ciencias Químicas
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Fluorescent fingerprints of edible oils and biodiesel by means total synchronous fluorescence and Tucker3 modeling
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-10-22T19:01:00Z
dc.journal.volume
175
dc.journal.pagination
185-190
dc.journal.pais
Estados Unidos
dc.description.fil
Fil: Insausti, Matías. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.description.fil
Fil: de Araújo Gomes, Adriano. Universidade Federal do Sul e Sudoeste do Pará; Brasil
dc.description.fil
Fil: Camiña, José Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Ciencias de la Tierra y Ambientales de La Pampa. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales. Instituto de Ciencias de la Tierra y Ambientales de La Pampa; Argentina
dc.description.fil
Fil: de Araújo, Mario Cesar Ugulino. Universidade Federal da Paraíba; Brasil
dc.description.fil
Fil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.journal.title
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.saa.2016.12.027
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S138614251630751X
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