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dc.contributor.author
Xu, Tao
dc.contributor.author
Waehler, Tobias
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Vecchietti, María Julia
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Bonivardi, Adrian Lionel
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Bauer, Tanja
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Schwegler, Johannes
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Schulz, Peter S.
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Wasserscheid, Peter
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Libuda, Joerg
dc.date.available
2018-11-01T17:09:03Z
dc.date.issued
2017-06
dc.identifier.citation
Xu, Tao; Waehler, Tobias; Vecchietti, María Julia; Bonivardi, Adrian Lionel; Bauer, Tanja; et al.; Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide; Wiley VCH Verlag; Angewandte Chemie; 56; 31; 6-2017; 9072-9076
dc.identifier.issn
1433-7851
dc.identifier.uri
http://hdl.handle.net/11336/63448
dc.description.abstract
Ionic liquids (IL) hold a great potential as novel electrolytes for applications in electronic materials and energy technology. The functionality of ILs in these applications relies on their interface to semiconducting nanomaterials. Therefore, methods to control the chemistry and structure of this interface are the key to assemble new IL-based electronic and electrochemical materials. Here, we present a new method to prepare a chemically well-defined interface between an oxide and an IL film. An imidazolium-based IL, which is carrying an ester group, is deposited onto cobalt oxide surface by evaporation. The IL binds covalently to the surface by thermally activated cleavage of the ester group and formation of a bridging carboxylate. The anchoring reaction shows high structure sensitivity, which implies that the IL film can be adhered selectively to specific oxide surfaces.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley VCH Verlag
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Chemical Anchoring
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Cobalt Oxide
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Ester Functionalization
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Ionic Liquids
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Vapor Deposition
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Otras Ciencias Químicas
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-10-23T20:52:01Z
dc.journal.volume
56
dc.journal.number
31
dc.journal.pagination
9072-9076
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Xu, Tao. Universitat Erlangen-Nuremberg; Alemania
dc.description.fil
Fil: Waehler, Tobias. Universitat Erlangen-Nuremberg; Alemania
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Fil: Vecchietti, María Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Bauer, Tanja. Universitat Erlangen-Nuremberg; Alemania
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Fil: Schwegler, Johannes. Universitat Erlangen-Nuremberg; Alemania
dc.description.fil
Fil: Schulz, Peter S.. Universitat Erlangen-Nuremberg; Alemania
dc.description.fil
Fil: Wasserscheid, Peter. Universitat Erlangen-Nuremberg; Alemania
dc.description.fil
Fil: Libuda, Joerg. Universitat Erlangen-Nuremberg; Alemania
dc.journal.title
Angewandte Chemie
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://doi.wiley.com/10.1002/anie.201704107
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/anie.201704107
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