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dc.contributor.author
Schulz, Eduardo Nicolás
dc.contributor.author
Salinas, Daniel Ricardo
dc.contributor.author
Garcia, Silvana Graciela
dc.date.available
2018-10-09T19:13:00Z
dc.date.issued
2010-04
dc.identifier.citation
Schulz, Eduardo Nicolás; Salinas, Daniel Ricardo; Garcia, Silvana Graciela; Electrodeposition of Rhodium onto a Pre-Treated Glassy Carbon Surface; Elsevier Science Inc; Electrochemistry Communications; 12; 4; 4-2010; 583-586
dc.identifier.issn
1388-2481
dc.identifier.uri
http://hdl.handle.net/11336/62000
dc.description.abstract
The electrodeposition of rhodium from a 0.5 M NaCl + 5 mM Na3RhCl6 solution onto an electrochemically activated glassy carbon (GC) electrode was investigated by cyclic voltammetry and chronoamperometry. The cyclic voltammogram showed the presence of two cathodic peaks associated with the deposition of Rh. The analysis of the chronoamperometric curves, according to the existing theories, indicated that the Rh electrodeposition can be explained by a combination of several nucleation processes: two-dimensional (2D) progressive nucleation, which transforms to 2D instantaneous nucleation at more cathodic potentials, followed by three-dimensional (3D) nucleation with diffusion controlled growth. The nucleation kinetic parameters were determined according to these theories. © 2010 Elsevier B.V. All rights reserved.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science Inc
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
2d-3d Transition
dc.subject
Glassy Carbon Substrate
dc.subject
Nucleation And Growth
dc.subject
Rhodium
dc.subject.classification
Nano-materiales
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Nanotecnología
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Electrodeposition of Rhodium onto a Pre-Treated Glassy Carbon Surface
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-09-18T15:02:31Z
dc.journal.volume
12
dc.journal.number
4
dc.journal.pagination
583-586
dc.journal.pais
Reino Unido
dc.journal.ciudad
Oxford
dc.description.fil
Fil: Schulz, Eduardo Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
dc.description.fil
Fil: Salinas, Daniel Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
dc.description.fil
Fil: Garcia, Silvana Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
dc.journal.title
Electrochemistry Communications
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1016/j.elecom.2010.02.005
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S138824811000069X


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