Artículo

Molecular transport properties of ZIF-8 thin films in aqueous environments: The critical role of intergrain mesoporosity as diffusional pathway

Tuninetti, Jimena SoledadIcon ; Rafti, MatiasIcon ; Andrieu Brunsen, Annette; Azzaroni, OmarIcon
Fecha de publicación: 01/2016
Editorial: Elsevier Science
Revista: Microporous and Mesoporous Materials
ISSN: 1387-1811
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

We report here the first use of electrochemical tools to quantify molecular transport from aqueous solutions into ZIF-8 MOF thin films. Our experimental findings reveal that molecular transport through ZIF-8 films in aqueous environments is purely dominated by solvent-filled intergrain mesoporosity and exhibits two well-defined transport regimes.
Palabras clave: Metal-Organic Frameworks , Molecular Transport , Thin Films , Zif-8
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/61582
DOI: https://dx.doi.org/10.1016/j.micromeso.2015.08.035
URL: https://www.sciencedirect.com/science/article/pii/S1387181115004655
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Articulos(INIFTA)
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Citación
Tuninetti, Jimena Soledad; Rafti, Matias; Andrieu Brunsen, Annette; Azzaroni, Omar; Molecular transport properties of ZIF-8 thin films in aqueous environments: The critical role of intergrain mesoporosity as diffusional pathway; Elsevier Science; Microporous and Mesoporous Materials; 220; 1-2016; 253-257
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