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dc.contributor.author
Testero, Sebastian Andres  
dc.contributor.author
Mangione, Maria Ines  
dc.contributor.author
Suarez, Alejandra Graciela  
dc.contributor.author
Spanevello, Rolando Angel  
dc.date.available
2016-06-06T21:20:41Z  
dc.date.issued
2013-05  
dc.identifier.citation
Testero, Sebastian Andres; Mangione, Maria Ines; Suarez, Alejandra Graciela; Spanevello, Rolando Angel; End-group differentiating ozonolysis of norbornene systems to access to highly substituted cyclopentane rings; Wiley; European Journal of Organic Chemistry; 2013; 24; 5-2013; 5236-5245  
dc.identifier.issn
1434-193X  
dc.identifier.uri
http://hdl.handle.net/11336/6075  
dc.description.abstract
The end-group-differentiating ozonolysis concept is discussed, with an emphasis on norbornene systems. Different remote functional groups in endo positions in norbornene derivatives are able to direct the primary ozonide fragmentation. By analysis of the factors affecting the regioselectivity, a rule to predict the direction of the primary ozonide rupture is formulated. These reactions give access to highly substituted cyclopentane rings and provide opportunities for their subsequent regioselective manipulation.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Wiley  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Cleavage Reactions  
dc.subject
Ozonolysis  
dc.subject
Primary Ozonide  
dc.subject
Substituent Effects  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
End-group differentiating ozonolysis of norbornene systems to access to highly substituted cyclopentane rings  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2016-06-01T13:35:41Z  
dc.journal.volume
2013  
dc.journal.number
24  
dc.journal.pagination
5236-5245  
dc.journal.pais
Alemania  
dc.journal.ciudad
Weinheim  
dc.description.fil
Fil: Testero, Sebastian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina  
dc.description.fil
Fil: Mangione, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina  
dc.description.fil
Fil: Suarez, Alejandra Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina  
dc.description.fil
Fil: Spanevello, Rolando Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina  
dc.journal.title
European Journal of Organic Chemistry  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201300384/abstract  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/10.1002/ejoc.201300384  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/ejoc.201300384  

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