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dc.contributor.author
Testero, Sebastian Andres
dc.contributor.author
Mangione, Maria Ines
dc.contributor.author
Suarez, Alejandra Graciela
dc.contributor.author
Spanevello, Rolando Angel
dc.date.available
2016-06-06T21:20:41Z
dc.date.issued
2013-05
dc.identifier.citation
Testero, Sebastian Andres; Mangione, Maria Ines; Suarez, Alejandra Graciela; Spanevello, Rolando Angel; End-group differentiating ozonolysis of norbornene systems to access to highly substituted cyclopentane rings; Wiley; European Journal of Organic Chemistry; 2013; 24; 5-2013; 5236-5245
dc.identifier.issn
1434-193X
dc.identifier.uri
http://hdl.handle.net/11336/6075
dc.description.abstract
The end-group-differentiating ozonolysis concept is discussed, with an emphasis on norbornene systems. Different remote functional groups in endo positions in norbornene derivatives are able to direct the primary ozonide fragmentation. By analysis of the factors affecting the regioselectivity, a rule to predict the direction of the primary ozonide rupture is formulated. These reactions give access to highly substituted cyclopentane rings and provide opportunities for their subsequent regioselective manipulation.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Cleavage Reactions
dc.subject
Ozonolysis
dc.subject
Primary Ozonide
dc.subject
Substituent Effects
dc.subject.classification
Química Orgánica
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
End-group differentiating ozonolysis of norbornene systems to access to highly substituted cyclopentane rings
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2016-06-01T13:35:41Z
dc.journal.volume
2013
dc.journal.number
24
dc.journal.pagination
5236-5245
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Testero, Sebastian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
dc.description.fil
Fil: Mangione, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
dc.description.fil
Fil: Suarez, Alejandra Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
dc.description.fil
Fil: Spanevello, Rolando Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
dc.journal.title
European Journal of Organic Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201300384/abstract
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/10.1002/ejoc.201300384
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/ejoc.201300384


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