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dc.contributor.author Testero, Sebastian Andres
dc.contributor.author Mangione, Maria Ines
dc.contributor.author Suarez, Alejandra Graciela
dc.contributor.author Spanevello, Rolando Angel
dc.date.available 2016-06-06T21:20:41Z
dc.date.issued 2013-05
dc.identifier.citation Testero, Sebastian Andres; Mangione, Maria Ines; Suarez, Alejandra Graciela; Spanevello, Rolando Angel; End-group differentiating ozonolysis of norbornene systems to access to highly substituted cyclopentane rings; Wiley; European Journal of Organic Chemistry; 2013; 24; 5-2013; 5236-5245
dc.identifier.issn 1434-193X
dc.identifier.uri http://hdl.handle.net/11336/6075
dc.description.abstract The end-group-differentiating ozonolysis concept is discussed, with an emphasis on norbornene systems. Different remote functional groups in endo positions in norbornene derivatives are able to direct the primary ozonide fragmentation. By analysis of the factors affecting the regioselectivity, a rule to predict the direction of the primary ozonide rupture is formulated. These reactions give access to highly substituted cyclopentane rings and provide opportunities for their subsequent regioselective manipulation.
dc.format application/pdf
dc.language.iso eng
dc.publisher Wiley
dc.rights info:eu-repo/semantics/restrictedAccess
dc.rights.uri https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject Cleavage reactions
dc.subject Ozonolysis
dc.subject Primary Ozonide
dc.subject Substituent effects
dc.subject.classification Química Orgánica
dc.subject.classification Ciencias Químicas
dc.subject.classification CIENCIAS NATURALES Y EXACTAS
dc.title End-group differentiating ozonolysis of norbornene systems to access to highly substituted cyclopentane rings
dc.type info:eu-repo/semantics/article
dc.type info:ar-repo/semantics/artículo
dc.type info:eu-repo/semantics/publishedVersion
dc.date.updated 2016-06-01T13:35:41Z
dc.journal.volume 2013
dc.journal.number 24
dc.journal.pagination 5236-5245
dc.journal.pais Alemania
dc.journal.ciudad Weinheim
dc.description.fil Fil: Testero, Sebastian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
dc.description.fil Fil: Mangione, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
dc.description.fil Fil: Suarez, Alejandra Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
dc.description.fil Fil: Spanevello, Rolando Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
dc.journal.title European Journal of Organic Chemistry
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201300384/abstract
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/doi/10.1002/ejoc.201300384
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/ejoc.201300384


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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)