Artículo
Catalytic oxidation of aqueous sulfide in the presence of ferrites (MFe2O4, M = Fe, Cu, Co)
Cunha, Igor T.; Teixeira, Ivo F.; Albuquerque, Adriana S.; Ardisson, José D.; Macedo, Waldemar A. A.; Oliveira, Henrique S.; Tristão, Juliana C.; Sapag, Manuel Karim
; Lago, Rochel M.
Fecha de publicación:
01/2016
Editorial:
Elsevier Science
Revista:
Catalysis Today
ISSN:
0920-5861
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
In this work, the spinel structured iron oxides, MFe2O4 (M = Cu2+ and Co2+), magnetite (Fe3O4) and maghemite (γ-Fe2O3) were investigated as catalyst for the sulfide oxidation in aqueous medium. XRD, Mössbauer, BET, TPR, SEM/EDS and XPS analyses suggest the formation of the spinel phase with surface areas varying from 75 to 105 m2 g-1 and the metal ions Cu2+ and Co2+ located in the octahedral and tetrahedral sites. It was observed that the presence of Co and especially Cu strongly increased the catalytic activity for the oxidation of sulfide to polysulfides, i.e. Sx 2- (x = 1-4) and other S-O species. The strong effect of Cu2+ is discussed in terms of thermodynamically favorable processes comprising a strong surface interaction of S2--Cu2+, an electron transfer from sulfide to produce Cu1+ followed by an electron transfer from Cu1+ to Fe3+ bulk.
Palabras clave:
Ferrite
,
Polysulfide
,
Sulfide Oxidation
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Articulos(INFAP)
Articulos de INST. DE FISICA APLICADA "DR. JORGE ANDRES ZGRABLICH"
Articulos de INST. DE FISICA APLICADA "DR. JORGE ANDRES ZGRABLICH"
Citación
Cunha, Igor T.; Teixeira, Ivo F.; Albuquerque, Adriana S.; Ardisson, José D.; Macedo, Waldemar A. A.; et al.; Catalytic oxidation of aqueous sulfide in the presence of ferrites (MFe2O4, M = Fe, Cu, Co); Elsevier Science; Catalysis Today; 259; 1-2016; 222-227
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