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dc.contributor.author Dieuzeide, María Laura
dc.contributor.author Laborde, Miguel Ángel
dc.contributor.author Amadeo, Norma Elvira
dc.contributor.author Cannilla, C.
dc.contributor.author Bonura, G.
dc.contributor.author Frusteri, F.
dc.date.available 2018-09-19T17:59:09Z
dc.date.issued 2016-01
dc.identifier.citation Dieuzeide, María Laura; Laborde, Miguel Ángel; Amadeo, Norma Elvira; Cannilla, C.; Bonura, G.; et al.; Hydrogen production by glycerol steam reforming: How Mg doping affects the catalytic behaviour of Ni/Al2O3 catalysts; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 41; 1; 1-2016; 157-166
dc.identifier.issn 0360-3199
dc.identifier.uri http://hdl.handle.net/11336/60253
dc.description.abstract Glycerol steam reforming, using Mg doped Ni/Al2O3 catalysts, was investigated with the aim to efficiently produce hydrogen. Catalyst containing different Mg loading were prepared by impregnation method maintaining constant the Ni loading (10 wt.%). Catalytic experiments were performed in fixed bed reactor operated at 500 and 600 °C. Characterization results revealed that Mg, further to infer a basic character to the carrier, promotes the Ni dispersion. In addition to observe that the catalytic activity was mainly dependent upon the Ni dispersion, the amount and morphology of coke formed during reaction was affected by Mg loading. In particular, the addition of 3wt% of Mg contributes to reduce the coke formation rate while a subsequent addition of Mg up to 10wt%, does not significantly affect neither the catalytic activity nor the carbon formation. By operating at 600 °C and with H2O/Gly ratio of 6, low amount of coke, mainly of filamentous nature, was formed. The size and structure of carbon filaments changed as a function of Ni particle size and Mg loading.
dc.format application/pdf
dc.language.iso eng
dc.publisher Pergamon-Elsevier Science Ltd
dc.rights info:eu-repo/semantics/restrictedAccess
dc.rights.uri https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject GLYCEROL STEAM REFORMING
dc.subject HYDROGEN PRODUCTION
dc.subject NI-MG CATALYSTS
dc.subject.classification Otras Ingeniería Química
dc.subject.classification Ingeniería Química
dc.subject.classification INGENIERÍAS Y TECNOLOGÍAS
dc.title Hydrogen production by glycerol steam reforming: How Mg doping affects the catalytic behaviour of Ni/Al2O3 catalysts
dc.type info:eu-repo/semantics/article
dc.type info:ar-repo/semantics/artículo
dc.type info:eu-repo/semantics/publishedVersion
dc.date.updated 2018-09-18T13:17:27Z
dc.journal.volume 41
dc.journal.number 1
dc.journal.pagination 157-166
dc.journal.pais Estados Unidos
dc.description.fil Fil: Dieuzeide, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
dc.description.fil Fil: Laborde, Miguel Ángel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
dc.description.fil Fil: Amadeo, Norma Elvira. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
dc.description.fil Fil: Cannilla, C.. Consiglio Nazionale delle Ricerche; Italia
dc.description.fil Fil: Bonura, G.. Consiglio Nazionale delle Ricerche; Italia
dc.description.fil Fil: Frusteri, F.. Consiglio Nazionale delle Ricerche; Italia
dc.journal.title International Journal of Hydrogen Energy
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.ijhydene.2015.12.009
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0360319915027536
dc.conicet.fuente unificacion


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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Atribución-NoComercial-SinDerivadas 2.5 Argentina (CC BY-NC-ND 2.5 AR)