Artículo
Arene cis-Diol Dehydrogenase-Catalysed Regio- and Stereoselective Oxidation of Arene-, Cycloalkane- and Cycloalkene-cis-diols to Yield Catechols and Chiral α-Ketols
Boyd, Derek R.; Sharma, Narain D.; Berberian, Victoria
; Cleij, Marcel; Hardacre, Christopher; Ljubez, Vera; McConville, Gareth; Stevenson, Paul J.; Kulakov, Leonid A.; Allen, Christopher C. R.
Fecha de publicación:
05/2015
Editorial:
Wiley VCH Verlag
Revista:
Advanced Synthesis & Catalysis (print)
ISSN:
1615-4150
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Benzene cis-diol dehydrogenase and naphthalene cis-diol dehydrogenase enzymes, expressed in Pseudomonas putida wild-type and Escherichia coli recombinant strains, were used to investigate regioselectivity and stereoselectivity during dehydrogenations of arene, cyclic alkane and cyclic alkene vicinal cis-diols. The dehydrogenase-catalysed production of enantiopure cis-diols, α-ketols and catechols, using benzene cis-diol dehydrogenase and naphthalene cis-diol dehydrogenase, involved both kinetic resolution and asymmetric synthesis methods. The chemoenzymatic production and applications of catechol bioproducts in synthesis were investigated.
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Articulos(CCT - MENDOZA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - MENDOZA
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - MENDOZA
Citación
Boyd, Derek R.; Sharma, Narain D.; Berberian, Victoria; Cleij, Marcel; Hardacre, Christopher; et al.; Arene cis-Diol Dehydrogenase-Catalysed Regio- and Stereoselective Oxidation of Arene-, Cycloalkane- and Cycloalkene-cis-diols to Yield Catechols and Chiral α-Ketols; Wiley VCH Verlag; Advanced Synthesis & Catalysis (print); 357; 8; 5-2015; 1881-1894
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