Artículo
XANES study of electronic and structural nature of Mn-sites in manganese oxides with catalytic properties
Figueroa, Santiago Jose Alejandro
; Requejo, Felix Gregorio
; Lede, Eduardo Javier
; Lamaita, Luciano; Peluso, Miguel Andrés
; Sambeth, Jorge Enrique
Fecha de publicación:
10/2005
Editorial:
Elsevier Science
Revista:
Catalysis Today
ISSN:
0920-5861
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The characterization of a series of manganese oxides prepared by different methods were performed by X-ray diffraction (XRD) and X-ray absorption near-edge structure (XANES) analysis. Low crystallized phases were found by means of XRD. The XANES results indicated that the mean oxidation state value of all the samples was between 3+ and 4+. XANES analysis of spectra and extended X-ray absorption fine structure (EXAFS) data revealed that Mn was present in three different octahedral environments; one of them corresponded to the environment of Mn in the pyrolusite phase while the other two can be associated to Mn in ramsdellite-like environment and Mn in a octahedral site with Mn-vacancies in the second shell of coordination. The different oxides were analyzed in the reaction of total oxidation of ethanol and we found that the catalytic activity was enhanced when the couple Mn3+-Mn4+ was present in the structure of the oxides.
Palabras clave:
Mn-Vacancies
,
Pca
,
Pyrolusite
,
Xanes
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(CINDECA)
Articulos de CENTRO DE INV EN CS.APLICADAS "DR.JORGE J.RONCO"
Articulos de CENTRO DE INV EN CS.APLICADAS "DR.JORGE J.RONCO"
Articulos(IFLP)
Articulos de INST.DE FISICA LA PLATA
Articulos de INST.DE FISICA LA PLATA
Citación
Figueroa, Santiago Jose Alejandro; Requejo, Felix Gregorio; Lede, Eduardo Javier; Lamaita, Luciano; Peluso, Miguel Andrés; et al.; XANES study of electronic and structural nature of Mn-sites in manganese oxides with catalytic properties; Elsevier Science; Catalysis Today; 107-108; 10-2005; 849-855
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