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dc.contributor.author
Herrero, Luis A.
dc.contributor.author
Cerro-Garrido, Juan Carlos
dc.contributor.author
Apella, Maria Cristina
dc.contributor.author
Terrón-Homar, Angel
dc.date.available
2018-08-16T21:42:18Z
dc.date.issued
2002-03
dc.identifier.citation
Herrero, Luis A.; Cerro-Garrido, Juan Carlos; Apella, Maria Cristina; Terrón-Homar, Angel; Interactions in solution of cobalt(II) and nickel(II) with nicotinamide adenine dinucleotide: A potentiometric and calorimetric study; Springer; Journal of Biological Inorganic Chemistry; 7; 3; 3-2002; 313-317
dc.identifier.issn
0949-8257
dc.identifier.uri
http://hdl.handle.net/11336/56041
dc.description.abstract
The equilibrium constants and the thermodynamic parameters enthalpy and entropy of the interaction between Ni(II) and Co(II) with NAD+ in aqueous solution were determined by calorimetry and potentiometry methods (ionic strength adjusted to 0.1 with sodium nitrate at 25 °C). The macrochelation of the systems was also studied. All the data, including the protonation enthalpy data of NAD+ (very similar to the protonation enthalpy of 5′-AMP) suggest a less restrictive model for the NAD+ "folded" conformation without intramolecular stacking between the bases, in agreement both with recent theoretical calculations and with the X-ray structure of trimethylene-bisadeninium or the free acid form of NAD+.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Springer
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Cobalt
dc.subject
Nickel
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Nicotinamide Adenine Dinucleotide Calorimetry
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Nucleotides
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Otras Ciencias Químicas
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Interactions in solution of cobalt(II) and nickel(II) with nicotinamide adenine dinucleotide: A potentiometric and calorimetric study
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-07-23T18:11:38Z
dc.identifier.eissn
1432-1327
dc.journal.volume
7
dc.journal.number
3
dc.journal.pagination
313-317
dc.journal.pais
Alemania
dc.journal.ciudad
Berlin
dc.description.fil
Fil: Herrero, Luis A.. Universitat de les Illes Balears. Departament de Química, Facultat de Ciencies; España
dc.description.fil
Fil: Cerro-Garrido, Juan Carlos. Universitat de les Illes Balears. Departament de Química, Facultat de Ciencies; España
dc.description.fil
Fil: Apella, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Centro de Referencia para Lactobacilos; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Naturales e Instituto Miguel Lillo; Argentina
dc.description.fil
Fil: Terrón-Homar, Angel. Universitat de les Illes Balears. Departament de Química, Facultat de Ciencies; España
dc.journal.title
Journal of Biological Inorganic Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1007/s00775-001-0300-8
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs00775-001-0300-8
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