Artículo
Influence of carbon support properties on the electrocatalytic activity of PtRuCu nanoparticles for methanol and ethanol oxidation
Fecha de publicación:
09/2017
Editorial:
Pergamon-Elsevier Science Ltd
Revista:
International Journal of Hydrogen Energy
ISSN:
0360-3199
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
This work set out to explore the influence of kind and surface condition of carbon supports on the electrocatalytic activity of trimetallic PtRuCu alloy nanoparticles. The structure, composition, particle size and catalyst loading were determined by XRD, EDX, XPS, TEM and ICP-AES analysis. XRD studies revealed that support physical characteristics and surface conditions have an important influence in lattice strain, while XPS pointed out that a strong electronic interaction exists between the particles and the carbon support. Electrochemical experiments showed that the activated carbon black supported PtRuCu catalyst exhibits the best performance for methanol and ethanol oxidation and the lowest poisoning rate. The superior catalytic activity of this electrode can be rationalized in terms of metal-support interaction, Pt utilization efficiency and electrical conductivity of the carbon support. Furthermore, the as-prepared electrode exhibits 13 and 7 times higher activity towards methanol and ethanol oxidation when compared with a PtRu/C commercial catalyst.
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Identificadores
Colecciones
Articulos(CCT - BAHIA BLANCA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - BAHIA BLANCA
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - BAHIA BLANCA
Articulos(IFISUR)
Articulos de INSTITUTO DE FISICA DEL SUR
Articulos de INSTITUTO DE FISICA DEL SUR
Citación
Comignani, Vanina; Sieben, Juan Manuel; Sanchez, Miguel Dario; Duarte, Marta María Elena; Influence of carbon support properties on the electrocatalytic activity of PtRuCu nanoparticles for methanol and ethanol oxidation; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 42; 39; 9-2017; 24785-24796
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