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Deactivation of H3PW12O40/TiO2 catalyst used in the production of camphene
Grzona, Liliana Myriam; Masini, Omar; Comelli, Nora Alejandra
; Ponzi, Esther Natalia
; Ponzi, Marta Isabel
; Ponzi, Esther Natalia
; Ponzi, Marta Isabel
Fecha de publicación:
01 -
2005
Editorial:
Springer
Revista:
Reaction Kinetics And Catalysis Letters
Idioma:
Inglés
http://dx.doi.org/10.1007/s11144-005-0026-7
https://link.springer.com/article/10.1007%2Fs11144-005-0026-7
https://link.springer.com/article/10.1007%2Fs11144-005-0026-7
Citación:
Grzona, Liliana Myriam; Masini, Omar; Comelli, Nora Alejandra; Ponzi, Esther Natalia; Ponzi, Marta Isabel; Deactivation of H3PW12O40/TiO2 catalyst used in the production of camphene; Springer; Reaction Kinetics And Catalysis Letters; 84; 1; 1-2005; 199-204
Resumen
The deactivation of the H3PW12O40 (HPW) catalyst supported on TiO2 used in the
isomerization reaction of α-pinene and its regeneration were studied. The
regeneration of the deactivated catalyst was carried out with an air flow at 300
and 500ºC, with an ozone-enriched oxygen flow at 150ºC and by extraction with
solvent and acid treatment. Only the last treatment permitted to recover its
activity restoring it in 48% of its initial value.
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