Artículo

A reliable one-pot synthesis of aryl azides from aryl amines using organotin azides as effective and recoverable reagents

Godoy Prieto, LeonelaIcon ; Lo Fiego, Marcos JacintoIcon ; Chopa, Alicia Beatriz; Lockhart, María Teresa
Fecha de publicación: 15/02/2017
Editorial: Elsevier Science Sa
Revista: Journal of Organometallic Chemistry
ISSN: 0022-328X
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

A mild and mass-efficient procedure based on the one-pot diazotization-azidodediazoniation of aromatic amines is described. A wide range of aryl azides are obtained in moderate to high yields by using tributyltin azide as an effective and reusable azide source in the presence of p-toluenesulfonic acid at room temperature. The method was also successfully applied employing an insoluble polymer-supported organotin azide.
Palabras clave: Aryl Azides , Azidodeamination , Diazotization-Azidodediazoniation , Polymer-Supported Organotin Azide , Recoverable Reagent , Tributyltin Azide
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
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URI: http://hdl.handle.net/11336/55394
URL: https://www.sciencedirect.com/science/article/pii/S0022328X16305502#!
DOI: http://dx.doi.org/10.1016/j.jorganchem.2016.11.037
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Citación
Godoy Prieto, Leonela; Lo Fiego, Marcos Jacinto; Chopa, Alicia Beatriz; Lockhart, María Teresa; A reliable one-pot synthesis of aryl azides from aryl amines using organotin azides as effective and recoverable reagents; Elsevier Science Sa; Journal of Organometallic Chemistry; 830; 15-2-2017; 26-32
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