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dc.contributor.author
Cornaglia, Laura Maria
dc.contributor.author
Múnera Agudelo, John Fernando
dc.contributor.author
Irusta, Silvia
dc.contributor.author
Lombardo, Eduardo Agustin
dc.date.available
2018-08-14T16:15:14Z
dc.date.issued
2004-05
dc.identifier.citation
Cornaglia, Laura Maria; Múnera Agudelo, John Fernando; Irusta, Silvia; Lombardo, Eduardo Agustin; Raman studies of Rh and Pt on La2O3 catalysts used in a membrane reactor for hydrogen production; Elsevier Science; Applied Catalysis A: General; 263; 1; 5-2004; 91-101
dc.identifier.issn
0926-860X
dc.identifier.uri
http://hdl.handle.net/11336/55378
dc.description.abstract
Rh and Pt catalysts supported on lanthanum oxide were prepared by wet impregnation. The solids were used in a Pd-Ag membrane reactor to produce hydrogen through the carbon dioxide reforming of methane. The effect of the sweep gas flow rate and W/F upon the conversions of CO2 and CH 4, as well as on the production of H2 was studied. The best performing catalyst was Rh (0.6%). It yielded a methane conversion 38% higher than the thermodynamic value and the highest H2 permeate flux across the membrane. Lanthanum phases on the support and the catalysts were characterized by Laser Raman spectroscopy, FTIR, and XRD. The support and the calcined fresh catalysts exhibited a mixture of phases which were influenced by the metal type. Furthermore, platinum seemed to favor the formation of Ia-La2O2CO3 after a short treatment in flowing CO2. However, the only remaining crystalline phase after 100h on stream was II-La2O2CO3. A small amount of graphitic carbon was detected using Laser Raman spectroscopy, despite the fact that no carbon deposition was observed through TGA measurements. The graphite crystallization order seemed to be dependent upon the contact time of the reactants.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
Carbon Deposits
dc.subject
Dry Reforming
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Lanthanum
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Membrane Reactor
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Raman Spectroscopy
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Otras Ingeniería Química
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Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Raman studies of Rh and Pt on La2O3 catalysts used in a membrane reactor for hydrogen production
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-08-13T18:15:14Z
dc.journal.volume
263
dc.journal.number
1
dc.journal.pagination
91-101
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Irusta, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.journal.title
Applied Catalysis A: General
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2003.12.003
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X03010226
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