Artículo
Self-assembled monolayers of thiolates on metals: A review article on sulfur-metal chemistry and surface structures
Vericat, Carolina
; Vela, Maria Elena; Corthey, Gastón; Pensa, Evangelina Laura
; Cortes, E.; Fonticelli, Mariano Hernan
; Ibañez, Francisco Javier
; Benitez, Guillermo Alfredo
; Carro, P.; Salvarezza, Roberto Carlos
Fecha de publicación:
06/2014
Editorial:
Royal Society of Chemistry
Revista:
RSC Advances
ISSN:
2046-2069
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
A review article on fundamental aspects of thiolate self-assembled monolayers (SAMs) on the (111) and (100) surfaces of the Cu and Ni groups is presented. In particular this work is focused on two important points that remain poorly understood in most of these metals: the chemistry of the S-metal interface, which strongly depends on the nature of the metallic surface, and the role of the interaction forces that not only guide the self-assembly process but also influence the surface structure of SAMs. In addition to recent experimental and theoretical data on these issues we present new density functional calculations including van der Waals forces for an important number of known thiolate surface structures as a function of the hydrocarbon chain length.
Palabras clave:
Self-Assembled Monolayers
,
Interfaces
,
Stm
,
Dft
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(INIFTA)
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Articulos(SEDE CENTRAL)
Articulos de SEDE CENTRAL
Articulos de SEDE CENTRAL
Citación
Vericat, Carolina; Vela, Maria Elena; Corthey, Gastón; Pensa, Evangelina Laura; Cortes, E.; et al.; Self-assembled monolayers of thiolates on metals: A review article on sulfur-metal chemistry and surface structures; Royal Society of Chemistry; RSC Advances; 4; 53; 6-2014; 27730-27754
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