Mostrar el registro sencillo del ítem

dc.contributor.author
Fernandez, Gabriela Araceli  
dc.contributor.author
Chopa, Alicia Beatriz  
dc.contributor.author
Silbestri, Gustavo Fabián  
dc.date.available
2018-08-08T20:59:17Z  
dc.date.issued
2016-02  
dc.identifier.citation
Fernandez, Gabriela Araceli; Chopa, Alicia Beatriz; Silbestri, Gustavo Fabián; A structure/catalytic activity study of gold(I)-NHC complexes, as well as their recyclability and reusability, in the hydration of alkynes in aqueous medium; Royal Society of Chemistry; Catalysis Science and Technology; 6; 6; 2-2016; 1921-1929  
dc.identifier.issn
2044-4753  
dc.identifier.uri
http://hdl.handle.net/11336/54700  
dc.description.abstract
We conducted a structure/catalytic activity study of water-soluble gold(i) complexes-supporting sulfonated NHC ligands-in the hydration of alkynes in pure water or water nsp;:nsp;methanol (1nsp;:nsp;1), as well as their recyclability. Comparative studies were carried out with the addition of different silver salts. Our results indicate that the bulkier complex is the most effective and that the addition of methanol as co-solvent not only shortens reaction times but also stabilizes the less bulky complexes.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Royal Society of Chemistry  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Carbenes  
dc.subject
Gold  
dc.subject
Alkynes  
dc.subject.classification
Otras Ciencias Químicas  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
A structure/catalytic activity study of gold(I)-NHC complexes, as well as their recyclability and reusability, in the hydration of alkynes in aqueous medium  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2018-08-01T14:28:11Z  
dc.identifier.eissn
2044-4761  
dc.journal.volume
6  
dc.journal.number
6  
dc.journal.pagination
1921-1929  
dc.journal.pais
Reino Unido  
dc.journal.ciudad
Cambridge  
dc.description.fil
Fil: Fernandez, Gabriela Araceli. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina  
dc.description.fil
Fil: Chopa, Alicia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina  
dc.description.fil
Fil: Silbestri, Gustavo Fabián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina  
dc.journal.title
Catalysis Science and Technology  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2016/cy/c5cy01278c#!divAbstract  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/C5CY01278C  

Archivos asociados
Thumbnail
 
Tamaño: 1.064Mb
Formato: PDF
.