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dc.contributor.author
Andreatta, Alfonsina Ester
dc.date.available
2018-08-08T18:33:10Z
dc.date.issued
2012-07-19
dc.identifier.citation
Andreatta, Alfonsina Ester; Liquid-liquid equilibria in ternary mixtures of methyl oleate + ethanol + glycerol at atmospheric pressure; American Chemical Society; Industrial & Engineering Chemical Research; 51; 28; 19-7-2012; 9642-9651
dc.identifier.issn
0888-5885
dc.identifier.uri
http://hdl.handle.net/11336/54623
dc.description.abstract
The knowledge and the ability to describe the phase equilibrium behavior of systems composed of transesterification products are very important in the optimization of biodiesel production and purification process. In this work, liquid-liquid equilibrium data have been measured for the ternary system methyl oleate + ethanol + glycerol, at temperatures between 303 and 333 K. This system has not been explored before. The experimental data measured were compared with analogous ternary systems showing an increasing of the solubility regarding the systems containing methanol. The isothermal experimental data have shown a good linear fit in an Othmer-Tobias plot. The group contribution with association GCA-EoS equation of state and the A-UNIFAC model were applied to represent the phase equilibria of this ternary system. The GCA-EoS model in particular, has shown a good predictive capability.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Methyl Oleate
dc.subject
Ethanol
dc.subject
Glycerol
dc.subject
Liquid-Liquid Equilibrium
dc.subject.classification
Otras Ingeniería Química
dc.subject.classification
Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Liquid-liquid equilibria in ternary mixtures of methyl oleate + ethanol + glycerol at atmospheric pressure
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-07-11T13:45:34Z
dc.journal.volume
51
dc.journal.number
28
dc.journal.pagination
9642-9651
dc.journal.pais
Estados Unidos
dc.journal.ciudad
Washington DC
dc.description.fil
Fil: Andreatta, Alfonsina Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina. Universidad Tecnológica Nacional. Facultad Regional San Francisco; Argentina
dc.journal.title
Industrial & Engineering Chemical Research
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ie301168r
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/ie301168r
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