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dc.contributor.author
Moglie, Yanina Fernanda
dc.contributor.author
González Soria, María José
dc.contributor.author
Martín García, Iris
dc.contributor.author
Radivoy, Gabriel Eduardo
dc.contributor.author
Alonso, Francisco
dc.date.available
2018-08-08T16:23:29Z
dc.date.issued
2016-05-26
dc.identifier.citation
Moglie, Yanina Fernanda; González Soria, María José; Martín García, Iris; Radivoy, Gabriel Eduardo; Alonso, Francisco; Catalyst- and solvent-free hydrophosphination and multicomponent hydrothiophosphination of alkenes and alkynes; Royal Society of Chemistry; Green Chemistry (print); 18; 18; 26-5-2016; 4896-4907
dc.identifier.issn
1463-9262
dc.identifier.uri
http://hdl.handle.net/11336/54585
dc.description.abstract
The hydrophosphination of carbon-carbon multiple bonds has been generally performed under acid, base or metal catalysis in different solvents. Herein, alkyl and alkenyl tertiary phosphines are obtained by the addition of diphenylphosphine to alkenes and alkynes, respectively, in the absence of a solvent and a catalyst. In the presence of elemental sulfur, the corresponding alkyl and alkenyl tertiary phosphine sulfides are synthesized in a three-component process. These simple methods, which meet most of the principles of Green Chemistry, are highly regioselective towards the anti-Markovnikov products and diastereoselective towards the Z alkenyl phosphines. The mechanistic aspects of the reactions are also tackled and the efficiency of the latter is compared with that of the catalytic methods.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.subject
Alkene Hydrophospination
dc.subject
Alkyne Hydrophosphination
dc.subject
Catalyst Free
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Solvent Free
dc.subject.classification
Otras Ciencias Químicas
dc.subject.classification
Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Catalyst- and solvent-free hydrophosphination and multicomponent hydrothiophosphination of alkenes and alkynes
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-08-01T14:27:47Z
dc.journal.volume
18
dc.journal.number
18
dc.journal.pagination
4896-4907
dc.journal.pais
Reino Unido
dc.journal.ciudad
Cambridge
dc.description.fil
Fil: Moglie, Yanina Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.description.fil
Fil: González Soria, María José. Universidad de Alicante, Alicante; España
dc.description.fil
Fil: Martín García, Iris. Universidad de Alicante, Alicante; España
dc.description.fil
Fil: Radivoy, Gabriel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.description.fil
Fil: Alonso, Francisco. Universidad de Alicante, Alicante; España
dc.journal.title
Green Chemistry (print)
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2016/gc/c6gc00903d#!divAbstrac
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/C6GC00903D
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