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dc.contributor.author
Moglie, Yanina Fernanda  
dc.contributor.author
González Soria, María José  
dc.contributor.author
Martín García, Iris  
dc.contributor.author
Radivoy, Gabriel Eduardo  
dc.contributor.author
Alonso, Francisco  
dc.date.available
2018-08-08T16:23:29Z  
dc.date.issued
2016-05-26  
dc.identifier.citation
Moglie, Yanina Fernanda; González Soria, María José; Martín García, Iris; Radivoy, Gabriel Eduardo; Alonso, Francisco; Catalyst- and solvent-free hydrophosphination and multicomponent hydrothiophosphination of alkenes and alkynes; Royal Society of Chemistry; Green Chemistry (print); 18; 18; 26-5-2016; 4896-4907  
dc.identifier.issn
1463-9262  
dc.identifier.uri
http://hdl.handle.net/11336/54585  
dc.description.abstract
The hydrophosphination of carbon-carbon multiple bonds has been generally performed under acid, base or metal catalysis in different solvents. Herein, alkyl and alkenyl tertiary phosphines are obtained by the addition of diphenylphosphine to alkenes and alkynes, respectively, in the absence of a solvent and a catalyst. In the presence of elemental sulfur, the corresponding alkyl and alkenyl tertiary phosphine sulfides are synthesized in a three-component process. These simple methods, which meet most of the principles of Green Chemistry, are highly regioselective towards the anti-Markovnikov products and diastereoselective towards the Z alkenyl phosphines. The mechanistic aspects of the reactions are also tackled and the efficiency of the latter is compared with that of the catalytic methods.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Royal Society of Chemistry  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc/2.5/ar/  
dc.subject
Alkene Hydrophospination  
dc.subject
Alkyne Hydrophosphination  
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Catalyst Free  
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Solvent Free  
dc.subject.classification
Otras Ciencias Químicas  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Catalyst- and solvent-free hydrophosphination and multicomponent hydrothiophosphination of alkenes and alkynes  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2018-08-01T14:27:47Z  
dc.journal.volume
18  
dc.journal.number
18  
dc.journal.pagination
4896-4907  
dc.journal.pais
Reino Unido  
dc.journal.ciudad
Cambridge  
dc.description.fil
Fil: Moglie, Yanina Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina  
dc.description.fil
Fil: González Soria, María José. Universidad de Alicante, Alicante; España  
dc.description.fil
Fil: Martín García, Iris. Universidad de Alicante, Alicante; España  
dc.description.fil
Fil: Radivoy, Gabriel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina  
dc.description.fil
Fil: Alonso, Francisco. Universidad de Alicante, Alicante; España  
dc.journal.title
Green Chemistry (print)  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2016/gc/c6gc00903d#!divAbstrac  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/C6GC00903D