Vanadium-substituted keggin type heteropolyacid are used for the selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide

Various types of aromatic and aliphatic sulfides are selectively oxidized to sulfoxides and sulfones with good to excellent yields using H2O2 35% p/V in the presence of catalytic amounts of Keggin heteropolyacid (H5PMo11Al0.5O40) using acetonitrile as solvent.

Palabras clave: Hydrogen Peroxide , Keggin Heteropolyacid , Oxidation , Sulfides , Sulfones , Sulfoxides

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Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)

Identificadores

URI: http://hdl.handle.net/11336/54147

DOI: http://dx.doi.org/10.2174/157017807782795592

URL: http://www.eurekaselect.com/81938/article

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Articulos(CINDECA)
Articulos de CENTRO DE INV EN CS.APLICADAS "DR.JORGE J.RONCO"

Citación

Romanelli, Gustavo Pablo; Bennardi, Daniel Oscar; Palermo, Valeria; Vazquez, Patricia Graciela; Tundo, Pietro; Vanadium-substituted keggin type heteropolyacid are used for the selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide; Bentham Science Publishers; Letters in Organic Chemistry; 4; 8; 12-2007; 544-549

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