Artículo

Influence of Structural Features of Tri-functionalized Aryl phosphates on the Outcome of the SRN1 Process with Stannyl Anions: a DFT Study

Dorn, VivianaIcon ; Silbestri, Gustavo FabiánIcon ; Lockhart, María Teresa; Chopa, Alicia Beatriz; Pierini, Adriana BeatrizIcon
Fecha de publicación: 02/2013
Editorial: Royal Society Of Chemistry
Revista: New Journal Of Chemistry
ISSN: 1144-0546
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Under irradiation, 1,3-bis(diethoxyphosphoryloxy)-4-chlorobenzene (2), 1,4-bis(diethoxyphosphoryloxy)-3-chlorobenzene (3) and 1,3-bis(diethoxyphosphoryloxy)-5-chlorobenzene (4) react with trimethyltinsodium(1) in liquid ammonia giving entirely different distribution of stannylated products. These differences are explained through theoretical DFT studies. Experimental evidence for the involvement of an SRN1 mechanism was obtained
Palabras clave: Aryl Phosphates , Srn1 , Stannyl Anions , Dft
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/5323
URL: http://pubs.rsc.org/en/content/articlelanding/2013/nj/c3nj40814k
DOI: http://dx.doi.org/10.1039/c3nj40814k
Colecciones
Articulos(CCT - BAHIA BLANCA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - BAHIA BLANCA
Articulos(CCT - CORDOBA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Articulos(INFIQC)
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Articulos(INQUISUR)
Articulos de INST.DE QUIMICA DEL SUR
Citación
Dorn, Viviana; Silbestri, Gustavo Fabián; Lockhart, María Teresa; Chopa, Alicia Beatriz; Pierini, Adriana Beatriz; Influence of Structural Features of Tri-functionalized Aryl phosphates on the Outcome of the SRN1 Process with Stannyl Anions: a DFT Study; Royal Society Of Chemistry; New Journal Of Chemistry; 37; 4; 2-2013; 1150-1156
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