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dc.contributor.author
Ruso, Juan M.
dc.contributor.author
Verdinelli, Valeria
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Hassan, Natalia
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Pieroni, Olga Inés
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Messina, Paula Veronica
dc.date.available
2016-04-21T15:01:51Z
dc.date.issued
2013-01
dc.identifier.citation
Ruso, Juan M.; Verdinelli, Valeria; Hassan, Natalia; Pieroni, Olga Inés; Messina, Paula Veronica; Enhancing CaP Biomimetic Growth on TiO2 Cuboids Nanoparticles via Highly Reactive Facets; American Chemical Society; Langmuir; 29; 7; 1-2013; 2350-2358
dc.identifier.issn
0743-7463
dc.identifier.uri
http://hdl.handle.net/11336/5304
dc.description.abstract
Pure decahedral anatase TiO2 particles with high content of reactive {001} facets were obtained from titanium(IV) tetrachloride (TiCl4) using a microemulsions droplet system at specific conditions as chemical microreactor. The product was systematically characterized by X-ray diffraction, field-emission scanning and transmission electron microscopy (FE-SEM, TEM), N2 adsorption-desorption isotherms, FT-IR and UV-vis spectroscopy, and photoluminescence studies. The obtained cuboids around 90 nm in size have a uniform and dense surface morphology with a BET specific surface area of 11.91 m(2) g(-1) and a band gap energy (3.18 eV) slightly inferior to the anatase dominated by the less-reactive {101} surface (3.20 eV). The presence of reactive facets on titania anatase favors the biomimetic growth of amorphous tricalcium phosphate after the first day of immersion in simulated human plasma. The results presented here can facilitate and improve the integration of anchored implants and enhance the biological responses to the soft tissues.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Anatase Tio2
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Microemulsions
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Cap
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Físico-Química, Ciencia de los Polímeros, Electroquímica
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Enhancing CaP Biomimetic Growth on TiO2 Cuboids Nanoparticles via Highly Reactive Facets
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2016-05-06 15:52:43.262787-03
dc.journal.volume
29
dc.journal.number
7
dc.journal.pagination
2350-2358
dc.journal.pais
Estados Unidos
dc.journal.ciudad
Washington
dc.description.fil
Fil: Ruso, Juan M.. Universidad de Santiago de Compostela. Departamento de Física Aplicada; España
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Fil: Verdinelli, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
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Fil: Hassan, Natalia. Universite Pierre et Marie Curie; Francia
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Fil: Pieroni, Olga Inés. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina
dc.description.fil
Fil: Messina, Paula Veronica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
dc.journal.title
Langmuir
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/pmid/23360423
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/10.1021/la305080x
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info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/la305080x
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info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/la305080x
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