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dc.contributor.author
Ferretti, Cristián Alejandro
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dc.contributor.author
Apesteguia, Carlos Rodolfo
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dc.contributor.author
Di Cosimo, Juana Isabel
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dc.date.available
2018-07-23T19:05:43Z
dc.date.issued
2011-05
dc.identifier.citation
Ferretti, Cristián Alejandro; Apesteguia, Carlos Rodolfo; Di Cosimo, Juana Isabel; MgO-based catalysts for monoglyceride synthesis from methyl oleate and glycerol: Effect of Li promotion; Elsevier Science; Applied Catalysis A: General; 399; 1-2; 5-2011; 146-153
dc.identifier.issn
0926-860X
dc.identifier.uri
http://hdl.handle.net/11336/52872
dc.description.abstract
The synthesis of monoglycerides (glyceryl monooleates) by heterogeneously catalyzed glycerolysis of an unsaturated fatty acid methyl ester (methyl oleate) was studied on MgO and Li-promoted MgO catalysts. Several MgO-based catalysts with different Li loadings were prepared by incipient wetness impregnation and characterized by XRD, N2 physisorption, and FTIR and TPD of CO 2 among other techniques. Promotion of MgO with lithium, a basic promoter, affected the textural and structural properties of the resulting oxides so that more crystalline MgO phases with decreased surface area were obtained at increasing Li contents. Furthermore, the addition of Li generated new strong base sites because of formation of dispersed surface Li2O species, and thereby increased the total base site density of parent MgO. Li-containing MgO catalysts efficiently promoted the glycerolysis reaction, achieving high monoglyceride yields (70-73%) at 493 K. The initial monoglyceride formation rate increased linearly with the Li content on the sample following the enhanced overall catalyst base strength. Although conversions at the end of the run were ≈100% for all the catalysts, the monoglyceride selectivity slightly decreased with the Li loading, probably as a consequence of the less surface affinity for glycerol adsorption that facilitates competing monoglyceride re-adsorption and transformation to diglycerides by consecutive glycerolysis or disproportionation reactions.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Base Catalysis
dc.subject
Fatty Acid Methyl Ester
dc.subject
Glycerol
dc.subject
Glycerolysis
dc.subject
Monoglyceride
dc.subject.classification
Otras Ingeniería Química
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dc.subject.classification
Ingeniería Química
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dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
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dc.title
MgO-based catalysts for monoglyceride synthesis from methyl oleate and glycerol: Effect of Li promotion
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-07-20T14:18:54Z
dc.journal.volume
399
dc.journal.number
1-2
dc.journal.pagination
146-153
dc.journal.pais
Países Bajos
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dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Ferretti, Cristián Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Di Cosimo, Juana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.journal.title
Applied Catalysis A: General
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2011.03.051
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X11001839
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