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dc.contributor.author
Osiry, Hernández
dc.contributor.author
Cano, A.
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Lemus Santana, Ana Adela
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Rodríguez, Alejandro
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Carbonio, Raul Ernesto
dc.contributor.author
Reguera, Edilso
dc.date.available
2018-07-18T18:27:51Z
dc.date.issued
2015-10
dc.identifier.citation
Osiry, Hernández; Cano, A.; Lemus Santana, Ana Adela; Rodríguez, Alejandro; Carbonio, Raul Ernesto; et al.; Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 230; 10-2015; 374-380
dc.identifier.issn
0022-4596
dc.identifier.uri
http://hdl.handle.net/11336/52591
dc.description.abstract
This contribution discusses the intercalation of imidazole and its 2-ethyl derivative, and pyridine in 2D copper nitroprusside. In the interlayer region, neighboring molecules remain interacting throu gh their dipole and quadrupole moments, which supports the solid 3D crystal structure. The crystal structure of this series of intercalation compounds was solved and refined from powder X-ray diffraction patterns complemented with spectroscopic information. The intermolecular interactions were studied from the refined crystal structures and low temperature magnetic measurements. Due to strong attractive forces between neighboring molecules, the resulting π–π cloud overlapping enables the ferromagnetic coupling between metal centers on neighboring layers, which was actually observed for the solids containing imidazole and pyridine as intercalated molecules. For these two solids, the magnetic data were properly described with a model of six neighbors. For the solid containing 2-ethylimidazole and for 2D copper nitroprusside, a model of four neighbors in a plane is sufficient to obtain a reliable data fitting.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Academic Press Inc Elsevier Science
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
2-D Copper Nitroprusside
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Intercalation of Organic Molecules
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Intermolecular Interactions
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Hybrid Inorganic Organic Solids
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Molecular Magnets
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Astronomía
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Ciencias Físicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-05-04T21:40:57Z
dc.journal.volume
230
dc.journal.pagination
374-380
dc.journal.pais
Estados Unidos
dc.description.fil
Fil: Osiry, Hernández. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
dc.description.fil
Fil: Cano, A.. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
dc.description.fil
Fil: Lemus Santana, Ana Adela. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
dc.description.fil
Fil: Rodríguez, Alejandro. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
dc.description.fil
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
dc.description.fil
Fil: Reguera, Edilso. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
dc.journal.title
Journal of Solid State Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022459615300931
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.jssc.2015.07.042
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