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dc.contributor.author
Del Rio, Daniel
dc.contributor.author
Sedran, Ulises Anselmo
dc.contributor.author
de la Puente, Gabriela
dc.date.available
2018-07-17T13:34:55Z
dc.date.issued
2012-12
dc.identifier.citation
Del Rio, Daniel; Sedran, Ulises Anselmo; de la Puente, Gabriela; Adsorption of sulfur compounds in the gasoline boiling range over FCC catalysts under process conditions; Berkeley Electronic Press; International Journal of Chemical Reactor Engineering; 10; 1; 12-2012; 10-15
dc.identifier.issn
1542-6580
dc.identifier.uri
http://hdl.handle.net/11336/52345
dc.description.abstract
Experiments on commercial FCC equilibrium catalysts with different hydrogen transfer properties and content of Ni and V contaminant metals were performed in a CREC Riser Simulator reactor to study the behavior of thiophenic compounds in the gasoline boiling range. Thiophene and alkylthiophenes were used as test reactants dissolved in aromatic and paraffinic solvents in usual concentrations of the process, from about 150 to 400 ppm of each compound. The experiments were performed under conditions similar to those of the industrial operation (510 º C, contact time 5 to 20 s). The reaction effluents were analyzed by on-line gas chromatography using two detectors simultaneously: FID (hydrocarbons) and PFPD (sulfur). The results showed that a higher hydrogen transfer capacity in a catalyst favors the decrease of the concentration of sulfur compounds in gasoline by adsorption and / or coke formation. These results were more pronounced as the molecular weight of the alkylthiophene increased. Reductions in total sulfur concentration in the gas phase as high as 65 % were observed. Among contaminant metals, Ni seemed to have an important contribution to this effect.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Berkeley Electronic Press
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Sulfur
dc.subject
Fuels
dc.subject
Fcc
dc.subject
Adsorption
dc.subject.classification
Otras Ingeniería Química
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Ingeniería Química
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INGENIERÍAS Y TECNOLOGÍAS
dc.title
Adsorption of sulfur compounds in the gasoline boiling range over FCC catalysts under process conditions
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-07-11T14:09:11Z
dc.journal.volume
10
dc.journal.number
1
dc.journal.pagination
10-15
dc.journal.pais
Estados Unidos
dc.description.fil
Fil: Del Rio, Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: de la Puente, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.journal.title
International Journal of Chemical Reactor Engineering
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1515/1542-6580.2870
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