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Artículo

Synergy between Graphene and Au Nanoparticles (Heterojunction) towards Quenching, Improving Raman Signal, and UV Light Sensing

Dalfovo, Maria CelesteIcon ; Lacconi, Gabriela InesIcon ; Moreno, Mónica; Yappert, Marta C.; Sumanasekera, Gamini U.; Salvarezza, Roberto CarlosIcon ; Ibañez, Francisco JavierIcon
Fecha de publicación: 04/2014
Editorial: American Chemical Society
Revista: Acs Applied Materials & Interfaces
ISSN: 1944-8244
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:
Físico-Química, Ciencia de los Polímeros, Electroquímica

Resumen

Here, we developed a simple method for obtaining a heterojunction composed of graphene (G) and surfactant-coated Au nanoparticles (NPs) to measure the film conductivity and surface enhanced Raman scattering (SERS). Monolayer G is obtained by chemical vapor deposition (CVD) and transferred via poly(methyl methacrylate) (PMMA) to microfabricated Au electrodes, glass, and silicon. Post-synthesis treatments of G with PMMA and ozone (O3) showed 1 and 6 orders of magnitude decrease in the conductivity, respectively. The heterojunction formation with Au NPs had no major effect on G conductivity. In this work is demonstrated that G quenches more than 90% of the combined photoluminescence and fluorescence of Au NPs and Rhodamine B (RhB), respectively. Signal quenching permitted quantitative analysis of SERS of RhB on various substrates including as-transferred graphene, oxidized graphene (OG), and the heterojunction. While G is mainly responsible for quenching photoluminescence and fluorescence, around 3 orders of magnitude increase SERS activity for RhB was accomplished by the heterojunction. Finally, we wanted to correlate changes in the current during UV light sensing experiments. We found striking differences in the sensing pro!les at different UV energies. KEYWORDS: graphene, nanoparticles, heterojunction, surface enhanced-Raman scattering, quenching, photoluminescence, and fluorescence.
Palabras clave: Graphene , Nanoparticles , Heterojunction , Sers , Quenching , Photoluminescence , Fluorescence
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/5026
DOI: http://dx.doi.org/ 10.1021/am405753t
URL: http://pubs.acs.org/doi/abs/10.1021/am405753t
DOI: http://dx.doi.org/10.1021/am405753t
Colecciones
Articulos(CCT - CORDOBA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Articulos(CCT - LA PLATA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - LA PLATA
Articulos(INFIQC)
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Articulos(INIFTA)
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Citación
Dalfovo, Maria Celeste; Lacconi, Gabriela Ines; Moreno, Mónica; Yappert, Marta C.; Sumanasekera, Gamini U.; et al.; Synergy between Graphene and Au Nanoparticles (Heterojunction) towards Quenching, Improving Raman Signal, and UV Light Sensing; American Chemical Society; Acs Applied Materials & Interfaces; 6; 9; 4-2014; 6384–6391
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