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dc.contributor.author
Flores, Federico Manuel  
dc.contributor.author
Undabeytia, Tomas  
dc.contributor.author
Morillo, Esmeralda  
dc.contributor.author
Torres Sanchez, Rosa Maria  
dc.date.available
2018-06-18T20:23:46Z  
dc.date.issued
2017-06  
dc.identifier.citation
Flores, Federico Manuel; Undabeytia, Tomas; Morillo, Esmeralda; Torres Sanchez, Rosa Maria; Technological applications of organo-montmorillonites in the removal of pyrimethanil from water: adsorption/desorption and flocculation studies; Springer Heidelberg; Environmental Science and Pollution Research; 24; 16; 6-2017; 14463-14476  
dc.identifier.issn
0944-1344  
dc.identifier.uri
http://hdl.handle.net/11336/49124  
dc.description.abstract
Pyrimethanil (2-aniline-4, 6-dimethylpyrimidine, PRM) is used in fruit packing plants to control fungal infections and diseases. The effluents greatly polluted with this fungicide, as a point source contamination, need to be technologically treated for their regeneration before they reach water bodies. This work evaluates the use of organo-montmorillonites, synthetized in our laboratory, for their application in adsorption and coagulation/flocculation processes for the removal of PRM from water. The adsorption-desorption performance of PRM in a raw montmorillonite (Mt) and several organo-montmorillonites (organo-Mt) obtained by different amounts and types of exchanged surfactants (octadecyltrimethylammonium (ODTMA) and didodecyldimethylammonium (DDAB) bromides and benzyltrimethylammonium chloride (BTMA)) was studied. The PRM adsorption on raw Mt was assigned mainly to an interlayer occupancy, while hydrophobic interactions between PRM and the surfactants in the exchanged samples increased PRM adsorption, which was correlated with the surfactant loading. PRM desorption showed irreversible behavior in raw Mt, which changed to reversible for organo-Mt samples, and was also correlated with the increase of surfactant loading. Two of the organo-Mt with high surfactant loading (twice the CEC) were assayed for the removal of commercial PRM in coagulation/flocculation tests, and their performance was compared to that of the native clay (Mt). The use of the organo-Mt produced flocculation at a very low ratio (0.5 g L−1), whereas no flocculation was observed with Mt. These results proved the feasibility of the use of organo-Mt for the treatment of wastewater contaminated with PRM using a low organo-Mt/liquid ratio.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Springer Heidelberg  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Adsorption  
dc.subject
Desorption  
dc.subject
Flocculation  
dc.subject
Montmorillonite  
dc.subject
Organo-Montmorillonite  
dc.subject
Pyrimethanil  
dc.subject.classification
Meteorología y Ciencias Atmosféricas  
dc.subject.classification
Ciencias de la Tierra y relacionadas con el Medio Ambiente  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Technological applications of organo-montmorillonites in the removal of pyrimethanil from water: adsorption/desorption and flocculation studies  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2018-06-18T14:19:57Z  
dc.identifier.eissn
1614-7499  
dc.journal.volume
24  
dc.journal.number
16  
dc.journal.pagination
14463-14476  
dc.journal.pais
Alemania  
dc.journal.ciudad
Heidelberg  
dc.description.fil
Fil: Flores, Federico Manuel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Consejo Superior de Investigaciones Científicas. Instituto de Investigaciones Agrobiológicas de Sevilla; España  
dc.description.fil
Fil: Undabeytia, Tomas. Consejo Superior de Investigaciones Científicas. Instituto de Investigaciones Agrobiológicas de Sevilla; España  
dc.description.fil
Fil: Morillo, Esmeralda. Consejo Superior de Investigaciones Científicas. Instituto de Investigaciones Agrobiológicas de Sevilla; España  
dc.description.fil
Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina  
dc.journal.title
Environmental Science and Pollution Research  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11356-017-9016-3  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1007/s11356-017-9016-3