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dc.contributor.author
Han, Lu  
dc.contributor.author
Zhang, Kan  
dc.contributor.author
Ishida, Hatsuo  
dc.contributor.author
Froimowicz, Pablo  
dc.date.available
2018-06-18T18:33:00Z  
dc.date.issued
2017-02-14  
dc.identifier.citation
Han, Lu; Zhang, Kan; Ishida, Hatsuo; Froimowicz, Pablo; Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 218; 18; 14-2-2017; 1-10;1600562  
dc.identifier.issn
1022-1352  
dc.identifier.uri
http://hdl.handle.net/11336/49055  
dc.description.abstract
Pure para and ortho position amide benzoxazines, pHBA-a and oHBA-a, are synthesized. The hydrogen bonding interactions occurring in pHBA-a and oHBA-a are studied by Fourier transform infrared (FT-IR) spectroscopy and proton nuclear magnetic resonance (1H NMR) spectroscopy. FT-IR results show that, while pHBA-a presents intermolecular hydrogen bonding interactions, oHBA-a exhibits an intramolecular five-membered-ring hydrogenbonding system between the NH in the amide group and the oxygen in the oxazine ring. Differential scanning calorimetry (DSC) is used to study the thermal properties of the resins and their respective polymers. A deeper understanding of the hydrogen bond interactions in this family of resins is attempted to have better insights on how these systems influence the polymerization behavior not only with respect to the polymerization temperature but also with respect to the propagation step.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Wiley VCH Verlag  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Benzoxazine  
dc.subject
Ft-Ir  
dc.subject
Hydrogen Bonding  
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Nmr  
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Polybenzoxazine  
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Recubrimientos y Películas  
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Ingeniería de los Materiales  
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INGENIERÍAS Y TECNOLOGÍAS  
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Otras Ciencias Químicas  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2018-06-06T19:43:37Z  
dc.journal.volume
218  
dc.journal.number
18  
dc.journal.pagination
1-10;1600562  
dc.journal.pais
Alemania  
dc.journal.ciudad
Weinheim  
dc.description.fil
Fil: Han, Lu. Case Western Reserve University; Estados Unidos  
dc.description.fil
Fil: Zhang, Kan. Jiangsu University; China  
dc.description.fil
Fil: Ishida, Hatsuo. Case Western Reserve University; Estados Unidos  
dc.description.fil
Fil: Froimowicz, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina  
dc.journal.title
Macromolecular Chemistry And Physics  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/macp.201600562  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/macp.201600562