Artículo

Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator

Yerien, Damián EmilioIcon ; Barata Vallejo, SebastianIcon ; Camps, B.; Cristófalo, Alejandro EzequielIcon ; Cano, María EmiliaIcon ; Uhrig, Maria LauraIcon ; Postigo, Jose AlbertoIcon
Fecha de publicación: 06/2017
Editorial: Royal Society of Chemistry
Revista: Catalysis Science and Technology
ISSN: 2044-4761
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biologically relevant sulfides are easily substituted with RF moieties employing a mild and environmentally benign radical strategy starting from readily available RFI.
Palabras clave: Perfluoroalkylation , (Tmeda) I.I3 , Photocatalyzed Reaction
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/48834
DOI: http://dx.doi.org/10.1039/C7CY00236J
URL: http://pubs.rsc.org/en/Content/ArticleLanding/2017/CY/C7CY00236J
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Articulos(OCA HOUSSAY)
Articulos de OFICINA DE COORDINACION ADMINISTRATIVA HOUSSAY
Citación
Yerien, Damián Emilio; Barata Vallejo, Sebastian; Camps, B.; Cristófalo, Alejandro Ezequiel; Cano, María Emilia; et al.; Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator; Royal Society of Chemistry; Catalysis Science and Technology; 7; 11; 6-2017; 2274-2282
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