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dc.contributor.author
Ruiz Varilla, Andrea M.  
dc.contributor.author
Baquero, Edwin A.  
dc.contributor.author
Silbestri, Gustavo Fabián  
dc.contributor.author
Gonzalez Arellano, Camino  
dc.contributor.author
de Jesús, Ernesto  
dc.contributor.author
Flores, Juan C.  
dc.date.available
2016-03-09T18:41:35Z  
dc.date.issued
2015-08  
dc.identifier.citation
Ruiz Varilla, Andrea M.; Baquero, Edwin A.; Silbestri, Gustavo Fabián; Gonzalez Arellano, Camino; de Jesús, Ernesto; et al.; Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes; Royal Society Of Chemistry; Dalton Transactions; 44; 42; 8-2015; 18360-18369  
dc.identifier.issn
1477-9226  
dc.identifier.uri
http://hdl.handle.net/11336/4713  
dc.description.abstract
A series of water-soluble (NHC)Pt(0)(dvtms) and (NHC)Pt(0)(AE) complexes containing different sulfonated NHC ligands (dvtms = divinyltetramethyldisiloxane and AE = diallyl ether) are reported. The dvtms compounds have been found to be quite robust and to display some conformational rigidity, whereas their AE counterparts are less stable and more flexible. The catalytic evaluation of these complexes in the hydrosilylation of alkynes in water revealed no benefits in favor of the complexes containing the more labile spectator diene (AE), and a fairly regular catalytic behavior for all complexes that restricts the location of the sulfonate group to the proximity of the metal site.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Royal Society Of Chemistry  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Nhc-Pt  
dc.subject
Sulfonated Nhc  
dc.subject.classification
Química Inorgánica y Nuclear  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2016-03-30 10:35:44.97925-03  
dc.journal.volume
44  
dc.journal.number
42  
dc.journal.pagination
18360-18369  
dc.journal.pais
Reino Unido  
dc.journal.ciudad
Cambridge  
dc.description.fil
Fil: Ruiz Varilla, Andrea M.. Universidad de Alcala. Facultad de Ciencias; España  
dc.description.fil
Fil: Baquero, Edwin A.. Universidad de Alcala. Facultad de Ciencias; España  
dc.description.fil
Fil: Silbestri, Gustavo Fabián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina  
dc.description.fil
Fil: Gonzalez Arellano, Camino. Universidad de Alcala. Facultad de Ciencias; España  
dc.description.fil
Fil: de Jesús, Ernesto. Universidad de Alcala. Facultad de Ciencias; España  
dc.description.fil
Fil: Flores, Juan C.. Universidad de Alcala. Facultad de Ciencias; España  
dc.journal.title
Dalton Transactions  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2015/DT/C5DT02622A#!divAbstract  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/c5dt02622a  

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