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dc.contributor.author
Dennehy, Mariana
dc.contributor.author
Delgado, Fermin
dc.contributor.author
Freire Espeleta, Eleonora
dc.contributor.author
Halac, Emilia Beatriz
dc.contributor.author
Baggio, Ricardo Fortunato
dc.date.available
2018-05-29T17:46:26Z
dc.date.issued
2016-06
dc.identifier.citation
Dennehy, Mariana; Delgado, Fermin; Freire Espeleta, Eleonora; Halac, Emilia Beatriz; Baggio, Ricardo Fortunato; A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C Structural Chemistry; 72; 7; 6-2016; 572-577
dc.identifier.issn
2053-2296
dc.identifier.uri
http://hdl.handle.net/11336/46449
dc.description.abstract
Silver(I) complexes with sulfur-donor ligands have a broad range of pharmacological applications. One of the most important factors for tuning the biological activity is the type of donor atom and the ease of ligand replacement. Silver thiosaccharinates display a wide range of structures from mono- to polynuclear complexes. We report the synthesis, crystal structure and vibrational spectroscopic analysis of a two-dimensional AgI-thiosaccharinate coordination polymer, namely poly[tris([mu]2-4,4'-bipyridine-[kappa]2N:N')bis([mu]3-1,1-dioxo-1,2-benzisothiazole-3-thiolato-[kappa]3N:S3:S3)bis([mu]2-1,1-dioxo-1,2-benzisothiazole-3-thiolato-[kappa]2S3:S3)tetrasilver(I)], [Ag2(C7H4NO2S2)2(C10H8N2)1.5]n, with 4,4'-bipyridine acting as a spacer. A relevant feature of the structure is the presence of an unusually short Ag...Ag separation of 2.8859 (10) Å, well within the range of argentophilic interactions and confirmed as such by Raman analysis of the low-frequency spectrum. From a topological point of view, the structure presents interpenetration in the form of a threefold entangled 2D[rightwards arrow]2D mesh (2D is two-dimensional).
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley Blackwell Publishing, Inc
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Two-Dimensional Silver(I) Coordination Polymer
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2d-2d Interpenetration
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Thiosaccharinate
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Argentophilic Interaction
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Crystal Structure
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Topological Analysis
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Raman
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Twinning
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Entangled Mesh
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Vibrational Spectroscopy
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Otras Ciencias Químicas
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-05-28T14:49:05Z
dc.journal.volume
72
dc.journal.number
7
dc.journal.pagination
572-577
dc.journal.pais
Reino Unido
dc.journal.ciudad
Londres
dc.description.fil
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.description.fil
Fil: Delgado, Fermin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.description.fil
Fil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
dc.description.fil
Fil: Halac, Emilia Beatriz. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
dc.description.fil
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
dc.journal.title
Acta Crystallographica Section C Structural Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1107/S2053229616009645
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2053229616009645
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