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dc.contributor.author
Blanco, Mirta Noemi
dc.contributor.author
Pizzio, Luis Rene
dc.contributor.author
Gorsd, Marina Noelia
dc.date.available
2016-03-04T15:54:45Z
dc.date.issued
2011-04-22
dc.identifier.citation
Blanco, Mirta Noemi; Pizzio, Luis Rene; Gorsd, Marina Noelia; Trifluoromethanesulfonic acid immobilized on zirconium oxide obtained by the sol-gel method as catalyst in paraben synthesis; Elsevier Science; Applied Catalysis A: General; 400; 1-2; 22-4-2011; 91-98
dc.identifier.issn
0926-860X
dc.identifier.uri
http://hdl.handle.net/11336/4617
dc.description.abstract
The parabens, alkylic esters of p-hydroxybenzoic acid, were synthesized using trifluoromethanesulfonic acid immobilized on zirconium oxide (zirconia) as catalyst. The oxide was obtained by the sol–gel method, using urea as a pore-forming agent. After removing urea by extraction with water, the solid was dried and then calcined at 100, 205, 310 and 425 ◦C for 24 h. Afterward, it was impregnated with trifluoromethanesulfonic acid in toluene at reflux and leached to remove the weakly adsorbed acid. Mesoporous materials were obtained, whose mean pore diameter increased with the temperature of the thermal treatment of the support, while the specific surface area and the amount of acid bonded to the support decreased. The samples are crystalline from 400 ◦C and are thermally stable up to 250 ◦C. The catalysts have strong acidity and the number of acid sites decreased with the acid content in the support. The catalytic activity in the synthesis of propyl paraben, expressed as moles of ester formed at 5 h/mol acid in the catalyst, decreased when samples obtained from supports thermally treated at higher temperature were used. The activity also slightly diminished for the synthesis of different parabens in the order propyl > ethyl > methyl ester.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
Trifluoromethanesulfonic Acid
dc.subject
Zirconium Oxide
dc.subject
Catalyst
dc.subject
Parabens
dc.subject.classification
Ingeniería de Procesos Químicos
dc.subject.classification
Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Trifluoromethanesulfonic acid immobilized on zirconium oxide obtained by the sol-gel method as catalyst in paraben synthesis
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2016-03-30 10:35:44.97925-03
dc.journal.volume
400
dc.journal.number
1-2
dc.journal.pagination
91-98
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
dc.description.fil
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
dc.description.fil
Fil: Gorsd, Marina Noelia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
dc.journal.title
Applied Catalysis A: General
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2011.04.018
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926860X11002365
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/issn/0926-860X
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