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dc.contributor.author
Cismondi Duarte, Martín
dc.contributor.author
Cruz Doblas, J.
dc.contributor.author
Gomez, M. J.
dc.contributor.author
Montoya, Gerardo Federico
dc.date.available
2018-05-02T13:33:59Z
dc.date.issued
2015-10-15
dc.identifier.citation
Cismondi Duarte, Martín; Cruz Doblas, J.; Gomez, M. J.; Montoya, Gerardo Federico; Modelling the phase behavior of alkane mixtures in wide ranges of conditions: New parameterization and predictive correlations of binary interactions for the RKPR EOS; Elsevier Science; Fluid Phase Equilibria; 403; 15-10-2015; 49-59
dc.identifier.issn
0378-3812
dc.identifier.uri
http://hdl.handle.net/11336/43792
dc.description.abstract
After showing in a previous publication a clear superiority to the classic Peng-Robinson EoS for the description of high pressure phase behavior in the more asymmetric alkane-alkane binary mixtures, in this work the RKPR EoS is turned into a predictive model by developing correlations of interaction parameters for all possible pairs or normal alkanes, associated also to a new parameterization of pure compounds. The proposed correlations are based on van der Waals quadratic mixing rules. Repulsive interaction lij parameters are implemented in all cases, while attractive kij interactions were necessary only for the methane-series and the more asymmetric systems of propane, in particular with carbon numbers higher than 24. The analysis of the results, in comparison to an important diversity of data available for several dozens of systems, demonstrates a very good predictive power for the new correlations, which could be useful in modeling the phase behavior of different hydrocarbon fluids.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Critical Lines
dc.subject
High Pressure Phase Behavior
dc.subject
Hydrocarbons
dc.subject
Interaction Parameters Correlation
dc.subject
Rkpr
dc.subject.classification
Otras Ingeniería Química
dc.subject.classification
Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Modelling the phase behavior of alkane mixtures in wide ranges of conditions: New parameterization and predictive correlations of binary interactions for the RKPR EOS
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-04-26T15:05:37Z
dc.journal.volume
403
dc.journal.pagination
49-59
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Cismondi Duarte, Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina. Universidad Nacional de Córdoba. Incubadora de Empresas; Argentina
dc.description.fil
Fil: Cruz Doblas, J.. Universidad Nacional de Córdoba. Incubadora de Empresas; Argentina
dc.description.fil
Fil: Gomez, M. J.. Universidad Nacional de Córdoba. Incubadora de Empresas; Argentina
dc.description.fil
Fil: Montoya, Gerardo Federico. Universidad Nacional de Córdoba. Incubadora de Empresas; Argentina
dc.journal.title
Fluid Phase Equilibria
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.fluid.2015.06.005
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0378381215003246?via%3Dihub
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