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dc.contributor.author
Iguchi, Daniela
dc.contributor.author
Erra Balsells, Rosa
dc.contributor.author
Bonesi, Sergio Mauricio
dc.date.available
2018-04-19T18:26:33Z
dc.date.issued
2016-01
dc.identifier.citation
Iguchi, Daniela; Erra Balsells, Rosa; Bonesi, Sergio Mauricio; Photo-Fries rearrangement of aryl acetamides: regioselectivity induced by the aqueous micellar green environment; Royal Society of Chemistry; Photochemical and Photobiological Sciences; 15; 1; 1-2016; 105-116
dc.identifier.issn
1474-905X
dc.identifier.uri
http://hdl.handle.net/11336/42709
dc.description.abstract
Photochemical reactions tend to give more than one photoproduct. However, such a reaction can be a powerful synthetic tool when it is possible to conduct it in regioselective conditions yielding a single photoproduct. Water–surfactant solutions as reaction media can be considered as an approach in this context because they show products with different features than those from isotropic solutions. Here we describe results obtained from studying the effect on the prototypical photoreaction, known as the photo-Fries reaction of several substituted acetanilides and α-naphthyl acetamide within surfactant micelles (ionic and non-ionic micelles). This reaction involves homolytic cleavage of a C–N bond to yield a singlet radical pair. The surfactant micelles control the rotational and translational mobility of the radical pair, resulting in noticeable photoproduct selectivity.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Photo-Fries
dc.subject
Micellas
dc.subject
Reordenamiento
dc.subject
Aectanilides
dc.subject.classification
Otras Ciencias Químicas
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Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Photo-Fries rearrangement of aryl acetamides: regioselectivity induced by the aqueous micellar green environment
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-04-13T14:34:56Z
dc.journal.volume
15
dc.journal.number
1
dc.journal.pagination
105-116
dc.journal.pais
Reino Unido
dc.description.fil
Fil: Iguchi, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
dc.description.fil
Fil: Erra Balsells, Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
dc.description.fil
Fil: Bonesi, Sergio Mauricio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
dc.journal.title
Photochemical and Photobiological Sciences
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1039/C5PP00349K
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2016/PP/C5PP00349K
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