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dc.contributor.author
Ruiz, Diego Manuel
dc.contributor.author
Autino, Juan Carlos
dc.contributor.author
Romanelli, Gustavo Pablo
dc.date.available
2018-04-16T21:42:43Z
dc.date.issued
2017-04
dc.identifier.citation
Ruiz, Diego Manuel; Autino, Juan Carlos; Romanelli, Gustavo Pablo; A Solvent-free Method for Synthesis of Dihydroangelicins using Microwaves; Bentham Science Publishers; Current Green Chemistry; 3; 3; 4-2017; 242-247
dc.identifier.issn
2213-3461
dc.identifier.uri
http://hdl.handle.net/11336/42230
dc.description.abstract
Background: Dihydrofurocoumarins are a large family of compounds, among them, dihydroangelicins and dihydropsoralens, are present in various plant species with varied biological activity. Several strategies have been developed for synthesizing these compounds and various catalysts have been used for this purpose. Methods: In this work, we report the synthesis of 8,9-dihydrofuran [2, 3-h] coumarins using allyloxycoumarin cycloaddition in sustainable conditions: absence of solvents, application of microwave radiation, and insoluble acid catalysis by means of heteropolyacids with Preyssler structure, [H14(NaP5MoW29O110)]. Conclusion: With these conditions, and testing sustainability by means of Eco-Scale and E-factor, we replace the use of solvents and mineral acids having a great impact on the environment with a solid, easily recoverable heteropolyacid.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Bentham Science Publishers
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Dihydroangelicins
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Dihydrofuocoumarins
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Microwave Radiation
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Green Chemistry
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Heteropolyacid
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Preyssler Structure
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Otras Ingeniería Química
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Ingeniería Química
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INGENIERÍAS Y TECNOLOGÍAS
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Otras Ciencias Químicas
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
A Solvent-free Method for Synthesis of Dihydroangelicins using Microwaves
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-04-05T18:36:15Z
dc.journal.volume
3
dc.journal.number
3
dc.journal.pagination
242-247
dc.journal.pais
India
dc.description.fil
Fil: Ruiz, Diego Manuel. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Catedra de Quimica Organica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
dc.description.fil
Fil: Autino, Juan Carlos. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Catedra de Quimica Organica; Argentina
dc.description.fil
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
dc.journal.title
Current Green Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.2174/2213346104666170224101037
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.eurekaselect.com/150409/article
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