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dc.contributor.author
Nieres, Pablo Daniel
dc.contributor.author
Zelin, Juan
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Trasarti, Andres Fernando
dc.contributor.author
Apesteguia, Carlos Rodolfo
dc.date.available
2018-04-16T13:57:20Z
dc.date.issued
2016-11
dc.identifier.citation
Nieres, Pablo Daniel; Zelin, Juan; Trasarti, Andres Fernando; Apesteguia, Carlos Rodolfo; Catalytic valorization of oil-derived fatty esters via cross-metathesis with nitriles; Wiley VCH Verlag; European Journal of Lipid Science and Technology; 118; 11; 11-2016; 1722-1729
dc.identifier.issn
1438-7697
dc.identifier.uri
http://hdl.handle.net/11336/42099
dc.description.abstract
The cross-metathesis of methyl oleate with 3-pentenenitrile to obtain 2-undecene, methyl 9-undecenoate, methyl 11-cyano-9-undecenoate and 3-dodecenenitrile was studied at 323 K in a batch reactor using second-generation Hoveyda-Grubbs (HG) catalysts. Self-metathesis of methyl oleate was the main undesired secondary reaction. For a 3-pentenenitrile/methyl oleate reactant ratio (R3PN/MO) of one, the yield (η_(C-M)) and selectivity (S_(C-M)) to cross-metathesis products were 47% and 63%, respectively. The formation of cross-metathesis products increased with increasing 3-pentene initial concentrations, essentially because the reaction equilibrium was shifted to higher methyl oleate conversions. Thus, η_(C-M) and S_(C-M) were 74% and 83%, respectively, at R3PN/MO = 5. Nevertheless, the HG complex was significantly deactivated when high R3PN/MO values were employed.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley VCH Verlag
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
3-PENTENENITRILE
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CROSS-METATHESIS
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HOVEYDA–GRUBBS CATALYSTS
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METHYL OLEATE
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OLEOCHEMISTRY
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Otras Ingeniería Química
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Ingeniería Química
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INGENIERÍAS Y TECNOLOGÍAS
dc.title
Catalytic valorization of oil-derived fatty esters via cross-metathesis with nitriles
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-04-13T13:55:12Z
dc.journal.volume
118
dc.journal.number
11
dc.journal.pagination
1722-1729
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Nieres, Pablo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Trasarti, Andres Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.journal.title
European Journal of Lipid Science and Technology
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1002/ejlt.201500611
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ejlt.201500611
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