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dc.contributor.author
Urrutia, Ignacio  
dc.date.available
2018-04-10T18:07:41Z  
dc.date.issued
2015-06  
dc.identifier.citation
Urrutia, Ignacio; Fluids confined in wedges and by edges: From cluster integrals to thermodynamic properties referred to different regions; American Institute of Physics; Journal of Chemical Physics; 142; 24; 6-2015; 1-7; 244902  
dc.identifier.issn
0021-9606  
dc.identifier.uri
http://hdl.handle.net/11336/41552  
dc.description.abstract
Recently, new insights into the relation between the geometry of the vessel that confines a fluid and its thermodynamic properties were traced through the study of cluster integrals for inhomogeneous fluids. In this work, I analyze the thermodynamic properties of fluids confined in wedges or by edges, emphasizing on the question of the region to which these properties refer. In this context, the relations between the line-thermodynamic properties referred to different regions are derived as analytic functions of the dihedral angle α, for 0 < α < 2π, which enables a unified approach to both edges and wedges. As a simple application of these results, I analyze the properties of the confined gas in the low-density regime. Finally, using recent analytic results for the second cluster integral of the confined hard sphere fluid, the low density behavior of the line thermodynamic properties is analytically studied up to order two in the density for 0 < α < 2π and by adopting different reference regions.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
American Institute of Physics  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Cluster Integrals  
dc.subject
Confined Fluids  
dc.subject
Edges Ans Wedges  
dc.subject
Colloids  
dc.subject.classification
Astronomía  
dc.subject.classification
Ciencias Físicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Fluids confined in wedges and by edges: From cluster integrals to thermodynamic properties referred to different regions  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2018-04-10T14:17:30Z  
dc.journal.volume
142  
dc.journal.number
24  
dc.journal.pagination
1-7; 244902  
dc.journal.pais
Estados Unidos  
dc.description.fil
Fil: Urrutia, Ignacio. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina  
dc.journal.title
Journal of Chemical Physics  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1063/1.4922928  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.4922928