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dc.contributor.author
Urrutia, Ignacio
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dc.date.available
2018-04-10T18:07:41Z
dc.date.issued
2015-06
dc.identifier.citation
Urrutia, Ignacio; Fluids confined in wedges and by edges: From cluster integrals to thermodynamic properties referred to different regions; American Institute of Physics; Journal of Chemical Physics; 142; 24; 6-2015; 1-7; 244902
dc.identifier.issn
0021-9606
dc.identifier.uri
http://hdl.handle.net/11336/41552
dc.description.abstract
Recently, new insights into the relation between the geometry of the vessel that confines a fluid and its thermodynamic properties were traced through the study of cluster integrals for inhomogeneous fluids. In this work, I analyze the thermodynamic properties of fluids confined in wedges or by edges, emphasizing on the question of the region to which these properties refer. In this context, the relations between the line-thermodynamic properties referred to different regions are derived as analytic functions of the dihedral angle α, for 0 < α < 2π, which enables a unified approach to both edges and wedges. As a simple application of these results, I analyze the properties of the confined gas in the low-density regime. Finally, using recent analytic results for the second cluster integral of the confined hard sphere fluid, the low density behavior of the line thermodynamic properties is analytically studied up to order two in the density for 0 < α < 2π and by adopting different reference regions.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Institute of Physics
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Cluster Integrals
dc.subject
Confined Fluids
dc.subject
Edges Ans Wedges
dc.subject
Colloids
dc.subject.classification
Astronomía
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dc.subject.classification
Ciencias Físicas
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dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
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dc.title
Fluids confined in wedges and by edges: From cluster integrals to thermodynamic properties referred to different regions
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-04-10T14:17:30Z
dc.journal.volume
142
dc.journal.number
24
dc.journal.pagination
1-7; 244902
dc.journal.pais
Estados Unidos
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dc.description.fil
Fil: Urrutia, Ignacio. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
dc.journal.title
Journal of Chemical Physics
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1063/1.4922928
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.4922928
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