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dc.contributor.author
Bacigalupe, Alejandro
dc.contributor.author
Poliszuk, Andrea K.
dc.contributor.author
Eisenberg, Patricia
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dc.contributor.author
Escobar, Mariano Martin
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dc.date.available
2018-04-10T15:27:00Z
dc.date.issued
2015-06
dc.identifier.citation
Bacigalupe, Alejandro; Poliszuk, Andrea K.; Eisenberg, Patricia; Escobar, Mariano Martin; Rheological behaviorandbondingperformanceofanalkalinesoy proteinsuspension; Elsevier; International Journal Of Adhesion And Adhesives; 62; 6-2015; 1-6
dc.identifier.issn
0143-7496
dc.identifier.uri
http://hdl.handle.net/11336/41504
dc.description.abstract
The goal of this work is to study the rheological properties of based-modified soy protein concentrate (SPC) adhesives and the relationship between viscoelastic properties and bonding performance. Chemical modification of SPC with sodium hydroxide was made to evaluate the effect of alkali on the viscoelastic properties. Viscosity and solubility depends directly of the 3D structure and the isoelectric point (pI) of the protein. Results show that viscosity is strongly pH dependant due to the protein unfolding. Solubility profiles exhibit the typical U-shaped curve, being higher on either side of isoelectric point. Fourier transformed infrared analysis was used to analyze Amide I (1720-1600 cm-1) and Amide III (1400-1200cm-1) band patterns which reflect the different secondary structures in proteins. The intensity of the band at 1250 cm-1 increases with respect to that at 1235 cm-1 for higher pH values. This could be associated with the destruction, at least partially, of the β-sheet structure. Bonding performance was measured in dry conditions and the wetting properties were analyzed by scanning electron microscopy. The bonding performance improves when the SPC is stabilized at pH 12 due to the protein unfolding, revealing a strong interaction between the secondary structure and the wood surface. As part of an ongoing project it was concluded that alkali modification is a suitable procedure to modify a protein suspension, improving application conditions and mechanical properties of bioadhesives of a semistructural type.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Wood Adhesives
dc.subject
Biodegradable
dc.subject
Rheology
dc.subject.classification
Recubrimientos y Películas
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dc.subject.classification
Ingeniería de los Materiales
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dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
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dc.title
Rheological behaviorandbondingperformanceofanalkalinesoy proteinsuspension
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-04-10T14:21:13Z
dc.journal.volume
62
dc.journal.pagination
1-6
dc.journal.pais
Países Bajos
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dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Bacigalupe, Alejandro. Instituto Nacional de Tecnología Industrial; Argentina
dc.description.fil
Fil: Poliszuk, Andrea K.. Instituto Nacional de Tecnología Industrial; Argentina
dc.description.fil
Fil: Eisenberg, Patricia. Instituto Nacional de Tecnología Industrial; Argentina
dc.description.fil
Fil: Escobar, Mariano Martin. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto Nacional de Tecnología Industrial; Argentina
dc.journal.title
International Journal Of Adhesion And Adhesives
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.ijadhadh.2015.06.004
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0143749615000834
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