Mostrar el registro sencillo del ítem
dc.contributor.author
Cozzarín, Melina Vanesa
dc.contributor.author
Tong, Shengrui
dc.contributor.author
Ge, Mao Fa
dc.contributor.author
Della Védova, Carlos Omar
dc.contributor.author
Romano, Rosana Mariel
dc.date.available
2018-04-03T22:03:13Z
dc.date.issued
2016-12
dc.identifier.citation
Cozzarín, Melina Vanesa; Tong, Shengrui; Ge, Mao Fa ; Della Védova, Carlos Omar; Romano, Rosana Mariel; Preparation and Spectroscopical Studies of FC(O)SSCl; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2016; 36; 12-2016; 5568-5574
dc.identifier.issn
1434-1948
dc.identifier.uri
http://hdl.handle.net/11336/40615
dc.description.abstract
The hitherto unknown FC(O)SSCl molecule was prepared by the reaction of ClC(O)SSCl with TlF in vacuum conditions. The molecule was characterized by its electron-impact mass spectrum, the IR spectrum in vapour phase, the Raman spectrum of the liquid, and also the matrix isolated FTIR spectra. FC(O)SSCl is composed by an equilibrium mixture of two conformers, syn-gauche and anti-gauche, both in vapour and liquid phases, with an approximately ratio of 80:20 %. The valence electronic properties were studied by means of photoelectron spectroscopy. The first ionization potential was observed at 10.14 eV, and the HOMO was assigned to the non-bonding electron lone pair located at the S atom bonded to the carbonyl group. A decrease in the dihedral angle of the S-S bond after ionization was predicted by quantum chemical calculations.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley VCH Verlag
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Conformation Analysis
dc.subject
Matrix Isolation
dc.subject
Photoelectron Spectroscopy
dc.subject
Sulfides
dc.subject
Vibrational Spectroscopy
dc.subject.classification
Otras Ciencias Químicas
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Preparation and Spectroscopical Studies of FC(O)SSCl
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-04-03T18:25:11Z
dc.journal.volume
2016
dc.journal.number
36
dc.journal.pagination
5568-5574
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Cozzarín, Melina Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
dc.description.fil
Fil: Tong, Shengrui. Chinese Academy of Sciences; República de China
dc.description.fil
Fil: Ge, Mao Fa. Chinese Academy of Sciences; República de China
dc.description.fil
Fil: Della Védova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
dc.description.fil
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
dc.journal.title
European Journal of Inorganic Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/ejic.201600966
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201600966
Archivos asociados
Tamaño:
1.946Mb
Formato:
PDF