Artículo

Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite

Anunziata, Oscar AlfredoIcon ; González Mercado, Griselda VerónicaIcon ; Pierella, Liliana BeatrizIcon
Fecha de publicación: 09/08/2004
Editorial: Elsevier Science
Revista: Catalysis Communications
ISSN: 1566-7367
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Significance of effective conversion of methane (C1) to more valuable compounds such as aromatics is studied using n-hexane (C6) as co-reactant. AH yield was as high as 30 mol% C using the following reaction conditions: temperature, 500 C; contact time w=f ¼30 g h mol 1 and a C1 molar fraction, XC1: ¼(C1/C1 +C6)¼0.60, was achieved. The effect of the contact time, molar fraction, and time on stream was analyzed in order to obtain more information about different species evolution. The C1 conversion reached at 50 mol% C using Zn/HZSM-11 with 2.13 mol Zn per cell unit.
Palabras clave: Zn/Hzsm-11 , Methane Activation , Hexane as Co-Reactan
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Atribución-NoComercial-SinDerivadas 2.5 Argentina (CC BY-NC-ND 2.5 AR)
Identificadores
URI: http://hdl.handle.net/11336/40586
URL: https://www.sciencedirect.com/science/article/pii/S1566736704000846
DOI: http://dx.doi.org/10.1016/j.catcom.2004.04.008
Colecciones
Articulos(CCT - CORDOBA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Articulos(CITEQ)
Articulos de CENTRO DE INVESTIGACION Y TECNOLOGIA QUIMICA
Citación
Anunziata, Oscar Alfredo; González Mercado, Griselda Verónica; Pierella, Liliana Beatriz; Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite; Elsevier Science; Catalysis Communications; 5; 8; 9-8-2004; 401-405
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