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Artículo

Simple thiol-ene click chemistry modification of SBA-15 silica pores with carboxylic acids

Bordoni, Andrea VeronicaIcon ; Lombardo, Maria VeronicaIcon ; Regazzoni, Alberto ErnestoIcon ; Soler Illia, Galo Juan de Avila ArturoIcon ; Wolosiuk, AlejandroIcon
Fecha de publicación: 07/2015
Editorial: Academic Press Inc Elsevier Science
Revista: Journal of Colloid and Interface Science
ISSN: 0021-9797
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:
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Resumen

A straightforward approach for anchoring tailored carboxylic groups in mesoporous SiO2 colloidal materials is presented. The thiol-ene photochemical reaction between vinyltrimethoxysilane precursors and various thiocarboxylic acids which has, click chemistry features (i.e. high conversion yields, insensitivity to oxygen, mild reaction conditions), results in carboxylated silane precursors that can be readily used as surface modifiers. The carboxylic groups of acetic, undecanoic and succinic acid were immobilized on the silica mesopore walls of SBA-15 powders employing the synthesized silane precursors. Post-grafting has been confirmed through infrared spectrometry (FTIR), energy dispersive X-ray spectroscopy (EDS), elemental analysis (EA) and zeta potential measurements. Detailed field-emission gun scanning electron microscopy (FESEM) images and small angle X-ray scattering (SAXS) data revealed parallel mesopores and ordered mesostructures. It is shown that the immobilized COOH groups are chemically accessible for acid-base reactions as well as copper adsorption. Immobilization of easily synthesized tailored carboxylic modified alkoxide precursors within mesoporous systems provides a unique chemical nanoenvironment within these ordered frameworks.
Palabras clave: Carboxylic Groups , Click Chemistry , Functionalized Sio≪Inf≫2≪/Inf≫ , Mesostructured Materials , Sba-15 , Thiol-Ene Addition
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/38385
DOI: http://dx.doi.org/10.1016/j.jcis.2015.03.030
URL: https://www.sciencedirect.com/science/article/pii/S0021979715002921
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Articulos(SEDE CENTRAL)
Articulos de SEDE CENTRAL
Citación
Bordoni, Andrea Veronica; Lombardo, Maria Veronica; Regazzoni, Alberto Ernesto; Soler Illia, Galo Juan de Avila Arturo; Wolosiuk, Alejandro; Simple thiol-ene click chemistry modification of SBA-15 silica pores with carboxylic acids; Academic Press Inc Elsevier Science; Journal of Colloid and Interface Science; 450; 7-2015; 316-324
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